Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate

The asymmetric unit of the title compound, (C(8)H(12)NO)(2)[Mn(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, consists of half an Mn(II) complex anion, a 2-meth­oxy­benyl­ammonium cation and a solvent water mol­ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa­h...

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Detalles Bibliográficos
Autores principales: Elboulali, Adel, Akriche, Samah, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884241/
https://www.ncbi.nlm.nih.gov/pubmed/24454017
http://dx.doi.org/10.1107/S1600536813026366
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author Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
author_facet Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
author_sort Elboulali, Adel
collection PubMed
description The asymmetric unit of the title compound, (C(8)H(12)NO)(2)[Mn(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, consists of half an Mn(II) complex anion, a 2-meth­oxy­benyl­ammonium cation and a solvent water mol­ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa­hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol­ecules. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). An intra­molecular N—H⋯O hydrogen bond is also observed.
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spelling pubmed-38842412014-01-17 Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate Elboulali, Adel Akriche, Samah Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(8)H(12)NO)(2)[Mn(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, consists of half an Mn(II) complex anion, a 2-meth­oxy­benyl­ammonium cation and a solvent water mol­ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa­hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol­ecules. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). An intra­molecular N—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884241/ /pubmed/24454017 http://dx.doi.org/10.1107/S1600536813026366 Text en © Elboulali et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title_full Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title_fullStr Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title_full_unstemmed Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title_short Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)manganate(II) dihydrate
title_sort bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) o,o′)manganate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884241/
https://www.ncbi.nlm.nih.gov/pubmed/24454017
http://dx.doi.org/10.1107/S1600536813026366
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AT rzaiguimohamed bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oomanganateiidihydrate

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