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Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]

The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral ge...

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Detalles Bibliográficos
Autores principales: Pan, Gang-Hong, Tang, Jin-Niu, Xu, Shi-Hua, Huang, Zhong-Jing, Mo, Bo-Fa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884242/
https://www.ncbi.nlm.nih.gov/pubmed/24454018
http://dx.doi.org/10.1107/S1600536813026524
Descripción
Sumario:The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral geometry. Two Cl atoms bridge two Zn(II) atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 4(4) net parallel to (001) when the dinuclear unit is considered as a node. O—H⋯O and O—H⋯Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water mol­ecules. Intra­layer π–π inter­actions between the triazole rings are observed [centroid–centroid distance = 3.716 (6) Å].