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Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]

The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral ge...

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Autores principales: Pan, Gang-Hong, Tang, Jin-Niu, Xu, Shi-Hua, Huang, Zhong-Jing, Mo, Bo-Fa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884242/
https://www.ncbi.nlm.nih.gov/pubmed/24454018
http://dx.doi.org/10.1107/S1600536813026524
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author Pan, Gang-Hong
Tang, Jin-Niu
Xu, Shi-Hua
Huang, Zhong-Jing
Mo, Bo-Fa
author_facet Pan, Gang-Hong
Tang, Jin-Niu
Xu, Shi-Hua
Huang, Zhong-Jing
Mo, Bo-Fa
author_sort Pan, Gang-Hong
collection PubMed
description The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral geometry. Two Cl atoms bridge two Zn(II) atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 4(4) net parallel to (001) when the dinuclear unit is considered as a node. O—H⋯O and O—H⋯Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water mol­ecules. Intra­layer π–π inter­actions between the triazole rings are observed [centroid–centroid distance = 3.716 (6) Å].
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spelling pubmed-38842422014-01-17 Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate] Pan, Gang-Hong Tang, Jin-Niu Xu, Shi-Hua Huang, Zhong-Jing Mo, Bo-Fa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral geometry. Two Cl atoms bridge two Zn(II) atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 4(4) net parallel to (001) when the dinuclear unit is considered as a node. O—H⋯O and O—H⋯Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water mol­ecules. Intra­layer π–π inter­actions between the triazole rings are observed [centroid–centroid distance = 3.716 (6) Å]. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884242/ /pubmed/24454018 http://dx.doi.org/10.1107/S1600536813026524 Text en © Pan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pan, Gang-Hong
Tang, Jin-Niu
Xu, Shi-Hua
Huang, Zhong-Jing
Mo, Bo-Fa
Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title_full Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title_fullStr Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title_full_unstemmed Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title_short Poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
title_sort poly[[μ-chlorido-μ-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-κ(2) n (4):n (4′)]-zinc] chloride dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884242/
https://www.ncbi.nlm.nih.gov/pubmed/24454018
http://dx.doi.org/10.1107/S1600536813026524
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