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Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate]
The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octahedral ge...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884242/ https://www.ncbi.nlm.nih.gov/pubmed/24454018 http://dx.doi.org/10.1107/S1600536813026524 |
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author | Pan, Gang-Hong Tang, Jin-Niu Xu, Shi-Hua Huang, Zhong-Jing Mo, Bo-Fa |
author_facet | Pan, Gang-Hong Tang, Jin-Niu Xu, Shi-Hua Huang, Zhong-Jing Mo, Bo-Fa |
author_sort | Pan, Gang-Hong |
collection | PubMed |
description | The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octahedral geometry. Two Cl atoms bridge two Zn(II) atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 4(4) net parallel to (001) when the dinuclear unit is considered as a node. O—H⋯O and O—H⋯Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water molecules. Intralayer π–π interactions between the triazole rings are observed [centroid–centroid distance = 3.716 (6) Å]. |
format | Online Article Text |
id | pubmed-3884242 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842422014-01-17 Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate] Pan, Gang-Hong Tang, Jin-Niu Xu, Shi-Hua Huang, Zhong-Jing Mo, Bo-Fa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[ZnCl(C(13)H(12)F(2)N(6)O)(2)]Cl·2H(2)O}(n), is a two-dimensional coordination polymer. The Zn(II) atom is six-coordinated by four N atoms from four 2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octahedral geometry. Two Cl atoms bridge two Zn(II) atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 4(4) net parallel to (001) when the dinuclear unit is considered as a node. O—H⋯O and O—H⋯Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water molecules. Intralayer π–π interactions between the triazole rings are observed [centroid–centroid distance = 3.716 (6) Å]. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884242/ /pubmed/24454018 http://dx.doi.org/10.1107/S1600536813026524 Text en © Pan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Pan, Gang-Hong Tang, Jin-Niu Xu, Shi-Hua Huang, Zhong-Jing Mo, Bo-Fa Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2) N (4):N (4′)]-zinc] chloride dihydrate] |
title | Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
N
(4):N
(4′)]-zinc] chloride dihydrate] |
title_full | Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
N
(4):N
(4′)]-zinc] chloride dihydrate] |
title_fullStr | Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
N
(4):N
(4′)]-zinc] chloride dihydrate] |
title_full_unstemmed | Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
N
(4):N
(4′)]-zinc] chloride dihydrate] |
title_short | Poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
N
(4):N
(4′)]-zinc] chloride dihydrate] |
title_sort | poly[[μ-chlorido-μ-[2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol-κ(2)
n
(4):n
(4′)]-zinc] chloride dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884242/ https://www.ncbi.nlm.nih.gov/pubmed/24454018 http://dx.doi.org/10.1107/S1600536813026524 |
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