Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]

The title dinuclear complex, [Fe(2)Br(4)(C(13)H(9)N(4))(2)], which lies on an inversion center, features two approximately planar bis­(pyridin-2-yl)pyrazole (bpypz(−)) ligands [maximum deviation = 0.082 (3) Å] and four bromide ions. Each Fe(III) ion is octa­hedrally coordinated by four N atoms of tw...

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Autores principales: Katsuta, Nagisa, Mishima, Akio, Fuyuhiro, Akira, Hayami, Shinya, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884243/
https://www.ncbi.nlm.nih.gov/pubmed/24454019
http://dx.doi.org/10.1107/S1600536813026573
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author Katsuta, Nagisa
Mishima, Akio
Fuyuhiro, Akira
Hayami, Shinya
Kawata, Satoshi
author_facet Katsuta, Nagisa
Mishima, Akio
Fuyuhiro, Akira
Hayami, Shinya
Kawata, Satoshi
author_sort Katsuta, Nagisa
collection PubMed
description The title dinuclear complex, [Fe(2)Br(4)(C(13)H(9)N(4))(2)], which lies on an inversion center, features two approximately planar bis­(pyridin-2-yl)pyrazole (bpypz(−)) ligands [maximum deviation = 0.082 (3) Å] and four bromide ions. Each Fe(III) ion is octa­hedrally coordinated by four N atoms of two bpypz(−) ligands and two Br ions. π–π stacking inter­actions [centroid–centroid distances = 3.7004 (17)–4.0123 (18) Å] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex mol­ecules.
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spelling pubmed-38842432014-01-17 Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)] Katsuta, Nagisa Mishima, Akio Fuyuhiro, Akira Hayami, Shinya Kawata, Satoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [Fe(2)Br(4)(C(13)H(9)N(4))(2)], which lies on an inversion center, features two approximately planar bis­(pyridin-2-yl)pyrazole (bpypz(−)) ligands [maximum deviation = 0.082 (3) Å] and four bromide ions. Each Fe(III) ion is octa­hedrally coordinated by four N atoms of two bpypz(−) ligands and two Br ions. π–π stacking inter­actions [centroid–centroid distances = 3.7004 (17)–4.0123 (18) Å] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex mol­ecules. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884243/ /pubmed/24454019 http://dx.doi.org/10.1107/S1600536813026573 Text en © Katsuta et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Katsuta, Nagisa
Mishima, Akio
Fuyuhiro, Akira
Hayami, Shinya
Kawata, Satoshi
Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title_full Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title_fullStr Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title_full_unstemmed Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title_short Bis[μ-3,5-bis­(pyridin-2-yl)-1H-pyrazole]­bis­[di­bromido­iron(III)]
title_sort bis[μ-3,5-bis­(pyridin-2-yl)-1h-pyrazole]­bis­[di­bromido­iron(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884243/
https://www.ncbi.nlm.nih.gov/pubmed/24454019
http://dx.doi.org/10.1107/S1600536813026573
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