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Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate

The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex a...

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Detalles Bibliográficos
Autores principales: Sarr, Modou, Diallo, Waly, Diasse-Sarr, Aminata, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/
https://www.ncbi.nlm.nih.gov/pubmed/24454022
http://dx.doi.org/10.1107/S1600536813026901
Descripción
Sumario:The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa­hedrally to the central Sn(IV) atom. The cohesion of the mol­ecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl inter­actions involving cations, anions and the lattice water mol­ecule, giving rise to a layer-like arrangement parallel to (010).