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Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2) O (1),O (2))stannate(IV) chloride monohydrate
The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/ https://www.ncbi.nlm.nih.gov/pubmed/24454022 http://dx.doi.org/10.1107/S1600536813026901 |
Sumario: | The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octahedrally to the central Sn(IV) atom. The cohesion of the molecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010). |
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