Cargando…
Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2) O (1),O (2))stannate(IV) chloride monohydrate
The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex a...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/ https://www.ncbi.nlm.nih.gov/pubmed/24454022 http://dx.doi.org/10.1107/S1600536813026901 |
_version_ | 1782298545478434816 |
---|---|
author | Sarr, Modou Diallo, Waly Diasse-Sarr, Aminata Plasseraud, Laurent Cattey, Hélène |
author_facet | Sarr, Modou Diallo, Waly Diasse-Sarr, Aminata Plasseraud, Laurent Cattey, Hélène |
author_sort | Sarr, Modou |
collection | PubMed |
description | The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octahedrally to the central Sn(IV) atom. The cohesion of the molecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010). |
format | Online Article Text |
id | pubmed-3884246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842462014-01-17 Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2) O (1),O (2))stannate(IV) chloride monohydrate Sarr, Modou Diallo, Waly Diasse-Sarr, Aminata Plasseraud, Laurent Cattey, Hélène Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octahedrally to the central Sn(IV) atom. The cohesion of the molecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010). International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884246/ /pubmed/24454022 http://dx.doi.org/10.1107/S1600536813026901 Text en © Sarr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sarr, Modou Diallo, Waly Diasse-Sarr, Aminata Plasseraud, Laurent Cattey, Hélène Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2) O (1),O (2))stannate(IV) chloride monohydrate |
title | Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) chloride monohydrate |
title_full | Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) chloride monohydrate |
title_fullStr | Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) chloride monohydrate |
title_full_unstemmed | Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) chloride monohydrate |
title_short | Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) chloride monohydrate |
title_sort | tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ(2)
o
(1),o
(2))stannate(iv) chloride monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/ https://www.ncbi.nlm.nih.gov/pubmed/24454022 http://dx.doi.org/10.1107/S1600536813026901 |
work_keys_str_mv | AT sarrmodou triscyclohexylammoniumcisdichloridobisoxalatok2o1o2stannateivchloridemonohydrate AT diallowaly triscyclohexylammoniumcisdichloridobisoxalatok2o1o2stannateivchloridemonohydrate AT diassesarraminata triscyclohexylammoniumcisdichloridobisoxalatok2o1o2stannateivchloridemonohydrate AT plasseraudlaurent triscyclohexylammoniumcisdichloridobisoxalatok2o1o2stannateivchloridemonohydrate AT catteyhelene triscyclohexylammoniumcisdichloridobisoxalatok2o1o2stannateivchloridemonohydrate |