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Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate

The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex a...

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Autores principales: Sarr, Modou, Diallo, Waly, Diasse-Sarr, Aminata, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/
https://www.ncbi.nlm.nih.gov/pubmed/24454022
http://dx.doi.org/10.1107/S1600536813026901
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author Sarr, Modou
Diallo, Waly
Diasse-Sarr, Aminata
Plasseraud, Laurent
Cattey, Hélène
author_facet Sarr, Modou
Diallo, Waly
Diasse-Sarr, Aminata
Plasseraud, Laurent
Cattey, Hélène
author_sort Sarr, Modou
collection PubMed
description The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa­hedrally to the central Sn(IV) atom. The cohesion of the mol­ecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl inter­actions involving cations, anions and the lattice water mol­ecule, giving rise to a layer-like arrangement parallel to (010).
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spelling pubmed-38842462014-01-17 Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate Sarr, Modou Diallo, Waly Diasse-Sarr, Aminata Plasseraud, Laurent Cattey, Hélène Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(6)H(14)N)(3)[Sn(C(2)O(4))(2)Cl(2)]Cl·H(2)O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa­hedrally to the central Sn(IV) atom. The cohesion of the mol­ecular entities is ensured by the formation of N—H⋯O, O—H⋯O, O—H⋯Cl and N—H⋯Cl inter­actions involving cations, anions and the lattice water mol­ecule, giving rise to a layer-like arrangement parallel to (010). International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884246/ /pubmed/24454022 http://dx.doi.org/10.1107/S1600536813026901 Text en © Sarr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarr, Modou
Diallo, Waly
Diasse-Sarr, Aminata
Plasseraud, Laurent
Cattey, Hélène
Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title_full Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title_fullStr Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title_full_unstemmed Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title_short Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) O (1),O (2))stann­ate(IV) chloride monohydrate
title_sort tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-κ(2) o (1),o (2))stann­ate(iv) chloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246/
https://www.ncbi.nlm.nih.gov/pubmed/24454022
http://dx.doi.org/10.1107/S1600536813026901
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