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Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)

The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four mol­ecules in the asymmetric unit. In the mol­ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular stru...

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Detalles Bibliográficos
Autores principales: Arularasan, P., B.Sivakumar, Chakkaravarthi, G., Mohan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884247/
https://www.ncbi.nlm.nih.gov/pubmed/24454023
http://dx.doi.org/10.1107/S1600536813026780
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author Arularasan, P.
B.Sivakumar,
Chakkaravarthi, G.
Mohan, R.
author_facet Arularasan, P.
B.Sivakumar,
Chakkaravarthi, G.
Mohan, R.
author_sort Arularasan, P.
collection PubMed
description The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four mol­ecules in the asymmetric unit. In the mol­ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C—H⋯O and N—H⋯Cl hydrogen bonds. The crystal structure exhibit weak inter­molecular N—H⋯O, C—H⋯O and N—H⋯Cl inter­actions, generating a three-dimensional network.
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spelling pubmed-38842472014-01-17 Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II) Arularasan, P. B.Sivakumar, Chakkaravarthi, G. Mohan, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four mol­ecules in the asymmetric unit. In the mol­ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C—H⋯O and N—H⋯Cl hydrogen bonds. The crystal structure exhibit weak inter­molecular N—H⋯O, C—H⋯O and N—H⋯Cl inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884247/ /pubmed/24454023 http://dx.doi.org/10.1107/S1600536813026780 Text en © Arularasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arularasan, P.
B.Sivakumar,
Chakkaravarthi, G.
Mohan, R.
Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title_full Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title_fullStr Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title_full_unstemmed Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title_short Bis(μ-l-arginine-κ(3) N (2),O:O′)bis­(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)
title_sort bis(μ-l-arginine-κ(3) n (2),o:o′)bis­(l-arginine-κ(2) n (2),o)tetra-μ-chlorido-tetra­chlorido­tetra­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884247/
https://www.ncbi.nlm.nih.gov/pubmed/24454023
http://dx.doi.org/10.1107/S1600536813026780
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