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Bis(μ-l-arginine-κ(3) N (2),O:O′)bis(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetrachloridotetracopper(II)
The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four molecules in the asymmetric unit. In the molecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular stru...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884247/ https://www.ncbi.nlm.nih.gov/pubmed/24454023 http://dx.doi.org/10.1107/S1600536813026780 |
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author | Arularasan, P. B.Sivakumar, Chakkaravarthi, G. Mohan, R. |
author_facet | Arularasan, P. B.Sivakumar, Chakkaravarthi, G. Mohan, R. |
author_sort | Arularasan, P. |
collection | PubMed |
description | The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four molecules in the asymmetric unit. In the molecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C—H⋯O and N—H⋯Cl hydrogen bonds. The crystal structure exhibit weak intermolecular N—H⋯O, C—H⋯O and N—H⋯Cl interactions, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3884247 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842472014-01-17 Bis(μ-l-arginine-κ(3) N (2),O:O′)bis(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) Arularasan, P. B.Sivakumar, Chakkaravarthi, G. Mohan, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(4)Cl(8)(C(6)H(14)N(4)O(2))(4)], contains four molecules in the asymmetric unit. In the molecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C—H⋯O and N—H⋯Cl hydrogen bonds. The crystal structure exhibit weak intermolecular N—H⋯O, C—H⋯O and N—H⋯Cl interactions, generating a three-dimensional network. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884247/ /pubmed/24454023 http://dx.doi.org/10.1107/S1600536813026780 Text en © Arularasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Arularasan, P. B.Sivakumar, Chakkaravarthi, G. Mohan, R. Bis(μ-l-arginine-κ(3) N (2),O:O′)bis(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title | Bis(μ-l-arginine-κ(3)
N
(2),O:O′)bis(l-arginine-κ(2)
N
(2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title_full | Bis(μ-l-arginine-κ(3)
N
(2),O:O′)bis(l-arginine-κ(2)
N
(2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title_fullStr | Bis(μ-l-arginine-κ(3)
N
(2),O:O′)bis(l-arginine-κ(2)
N
(2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title_full_unstemmed | Bis(μ-l-arginine-κ(3)
N
(2),O:O′)bis(l-arginine-κ(2)
N
(2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title_short | Bis(μ-l-arginine-κ(3)
N
(2),O:O′)bis(l-arginine-κ(2)
N
(2),O)tetra-μ-chlorido-tetrachloridotetracopper(II) |
title_sort | bis(μ-l-arginine-κ(3)
n
(2),o:o′)bis(l-arginine-κ(2)
n
(2),o)tetra-μ-chlorido-tetrachloridotetracopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884247/ https://www.ncbi.nlm.nih.gov/pubmed/24454023 http://dx.doi.org/10.1107/S1600536813026780 |
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