Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate

In the title compound, [Cu(C(6)H(5)BrNO)(2)]·H(2)O, the Cu(II) ion has a square-planer N(2)O(2) coordination environment. Slipped π–π stackings [centroid-centroid distances: 3.625 (3), 3.767 (3), 3.935 (3) and 4.255 (3) Å] between pyridine rings and Cu⋯π inter­actions (centroid-to-Cu(II) distance: 3...

Descripción completa

Detalles Bibliográficos
Autores principales: Hamaguchi, Tomohiko, Kawahara, Issei, Ando, Isao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884248/
https://www.ncbi.nlm.nih.gov/pubmed/24454024
http://dx.doi.org/10.1107/S1600536813026974
_version_ 1782298545959731200
author Hamaguchi, Tomohiko
Kawahara, Issei
Ando, Isao
author_facet Hamaguchi, Tomohiko
Kawahara, Issei
Ando, Isao
author_sort Hamaguchi, Tomohiko
collection PubMed
description In the title compound, [Cu(C(6)H(5)BrNO)(2)]·H(2)O, the Cu(II) ion has a square-planer N(2)O(2) coordination environment. Slipped π–π stackings [centroid-centroid distances: 3.625 (3), 3.767 (3), 3.935 (3) and 4.255 (3) Å] between pyridine rings and Cu⋯π inter­actions (centroid-to-Cu(II) distance: 3.56 Å) between Cu(2+) ions and pyridine rings lead to a layered arrangement parallel to (010). Inter­molecular Br⋯O inter­actions [Br⋯O distances: 2.904 (3) and 3.042 (3) Å] and O—H⋯O hydrogen bonds form a three-dimensional network structure.
format Online
Article
Text
id pubmed-3884248
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38842482014-01-17 Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate Hamaguchi, Tomohiko Kawahara, Issei Ando, Isao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(5)BrNO)(2)]·H(2)O, the Cu(II) ion has a square-planer N(2)O(2) coordination environment. Slipped π–π stackings [centroid-centroid distances: 3.625 (3), 3.767 (3), 3.935 (3) and 4.255 (3) Å] between pyridine rings and Cu⋯π inter­actions (centroid-to-Cu(II) distance: 3.56 Å) between Cu(2+) ions and pyridine rings lead to a layered arrangement parallel to (010). Inter­molecular Br⋯O inter­actions [Br⋯O distances: 2.904 (3) and 3.042 (3) Å] and O—H⋯O hydrogen bonds form a three-dimensional network structure. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884248/ /pubmed/24454024 http://dx.doi.org/10.1107/S1600536813026974 Text en © Hamaguchi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hamaguchi, Tomohiko
Kawahara, Issei
Ando, Isao
Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title_full Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title_fullStr Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title_full_unstemmed Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title_short Bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) N,O]copper(II) monohydrate
title_sort bis[(5-bromo­pyridin-2-yl)methano­lato-κ(2) n,o]copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884248/
https://www.ncbi.nlm.nih.gov/pubmed/24454024
http://dx.doi.org/10.1107/S1600536813026974
work_keys_str_mv AT hamaguchitomohiko bis5bromopyridin2ylmethanolatok2nocopperiimonohydrate
AT kawaharaissei bis5bromopyridin2ylmethanolatok2nocopperiimonohydrate
AT andoisao bis5bromopyridin2ylmethanolatok2nocopperiimonohydrate

Ejemplares similares