Cargando…

catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]

In the title compound, {[Pr(C(14)H(8)O(5))(C(14)H(9)O(5))(H(2)O)(2)]·H(2)O}(n), the Pr(III) cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­act...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Ping, Su, Duo-Meng, Zheng, Chang-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884249/
https://www.ncbi.nlm.nih.gov/pubmed/24454025
http://dx.doi.org/10.1107/S1600536813026421
Descripción
Sumario:In the title compound, {[Pr(C(14)H(8)O(5))(C(14)H(9)O(5))(H(2)O)(2)]·H(2)O}(n), the Pr(III) cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­action), and two O-atom donors from water mol­ecules. A single water mol­ecule of solvation is also present. The complex units are linked through carboxyl O:O′ bridges giving a two-dimensional sheet polymer lying parallel to (001). An overall three-dimensional network structure is generated through inter­molecular carb­oxy­lic acid and water O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions.