catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]

In the title compound, {[Pr(C(14)H(8)O(5))(C(14)H(9)O(5))(H(2)O)(2)]·H(2)O}(n), the Pr(III) cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­act...

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Detalles Bibliográficos
Autores principales: Li, Ping, Su, Duo-Meng, Zheng, Chang-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884249/
https://www.ncbi.nlm.nih.gov/pubmed/24454025
http://dx.doi.org/10.1107/S1600536813026421
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author Li, Ping
Su, Duo-Meng
Zheng, Chang-Ge
author_facet Li, Ping
Su, Duo-Meng
Zheng, Chang-Ge
author_sort Li, Ping
collection PubMed
description In the title compound, {[Pr(C(14)H(8)O(5))(C(14)H(9)O(5))(H(2)O)(2)]·H(2)O}(n), the Pr(III) cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­action), and two O-atom donors from water mol­ecules. A single water mol­ecule of solvation is also present. The complex units are linked through carboxyl O:O′ bridges giving a two-dimensional sheet polymer lying parallel to (001). An overall three-dimensional network structure is generated through inter­molecular carb­oxy­lic acid and water O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions.
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spelling pubmed-38842492014-01-17 catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate] Li, Ping Su, Duo-Meng Zheng, Chang-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Pr(C(14)H(8)O(5))(C(14)H(9)O(5))(H(2)O)(2)]·H(2)O}(n), the Pr(III) cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­action), and two O-atom donors from water mol­ecules. A single water mol­ecule of solvation is also present. The complex units are linked through carboxyl O:O′ bridges giving a two-dimensional sheet polymer lying parallel to (001). An overall three-dimensional network structure is generated through inter­molecular carb­oxy­lic acid and water O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884249/ /pubmed/24454025 http://dx.doi.org/10.1107/S1600536813026421 Text en © Li et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ping
Su, Duo-Meng
Zheng, Chang-Ge
catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title_full catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title_fullStr catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title_full_unstemmed catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title_short catena-Poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(III)] monohydrate]
title_sort catena-poly[[di­aqua­[μ(2)-4-(4-carb­oxy­phen­oxy)benzoato](μ(2)-4,4′-oxydibenzo­ato)praseodymium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884249/
https://www.ncbi.nlm.nih.gov/pubmed/24454025
http://dx.doi.org/10.1107/S1600536813026421
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AT suduomeng catenapolydiaquam244carboxyphenoxybenzoatom244oxydibenzoatopraseodymiumiiimonohydrate
AT zhengchangge catenapolydiaquam244carboxyphenoxybenzoatom244oxydibenzoatopraseodymiumiiimonohydrate

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