[2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)

The title compound, [Ir(C(10)H(5)F(2)N(2))(2)(C(5)H(7)O(2))], has a distorted octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral...

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Detalles Bibliográficos
Autores principales: Luo, Kaijun, Zhang, Chenyang, Jia, Juan, Luo, Daibing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884251/
https://www.ncbi.nlm.nih.gov/pubmed/24454027
http://dx.doi.org/10.1107/S1600536813026160
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author Luo, Kaijun
Zhang, Chenyang
Jia, Juan
Luo, Daibing
author_facet Luo, Kaijun
Zhang, Chenyang
Jia, Juan
Luo, Daibing
author_sort Luo, Kaijun
collection PubMed
description The title compound, [Ir(C(10)H(5)F(2)N(2))(2)(C(5)H(7)O(2))], has a distorted octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol­ecular structure is stabilized by weak C—H⋯O and C—H⋯F hydrogen-bond inter­actions. The crystal structure is stabilized by π–π stacking inter­actions (centroid–centroid distance = 3.951 Å).
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spelling pubmed-38842512014-01-17 [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III) Luo, Kaijun Zhang, Chenyang Jia, Juan Luo, Daibing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ir(C(10)H(5)F(2)N(2))(2)(C(5)H(7)O(2))], has a distorted octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol­ecular structure is stabilized by weak C—H⋯O and C—H⋯F hydrogen-bond inter­actions. The crystal structure is stabilized by π–π stacking inter­actions (centroid–centroid distance = 3.951 Å). International Union of Crystallography 2013-10-09 /pmc/articles/PMC3884251/ /pubmed/24454027 http://dx.doi.org/10.1107/S1600536813026160 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Kaijun
Zhang, Chenyang
Jia, Juan
Luo, Daibing
[2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title_full [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title_fullStr [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title_full_unstemmed [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title_short [2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta­ne-2,4-dionato-κ(2) O,O′)iridium(III)
title_sort [2,6-di­fluoro-3-(pyridin-2-yl-κn)pyridin-4-yl-κc (4)](penta­ne-2,4-dionato-κ(2) o,o′)iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884251/
https://www.ncbi.nlm.nih.gov/pubmed/24454027
http://dx.doi.org/10.1107/S1600536813026160
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