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Di-μ-acetato-κ(4) O:O′-bis[(1,10-phenanthroline-κ(2) N,N′)(trifluoromethanesulfonato-κO)copper(II)]
The complete molecule of the title compound, [Cu(2)(C(2)H(3)O(2))(2)(CF(3)O(3)S)(2)(C(12)H(8)N(2))(2)], is completed by the application of a twofold rotation and comprises two Cu(II) ions, each of which is pentacoordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O ato...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884252/ https://www.ncbi.nlm.nih.gov/pubmed/24454028 http://dx.doi.org/10.1107/S1600536813027323 |
Sumario: | The complete molecule of the title compound, [Cu(2)(C(2)H(3)O(2))(2)(CF(3)O(3)S)(2)(C(12)H(8)N(2))(2)], is completed by the application of a twofold rotation and comprises two Cu(II) ions, each of which is pentacoordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O atoms from acetate ligands and an O atom from a trifluoromethanesulfonate anion, forming a (4 + 1) distorted square-pyramidal coordination geometry. The Cu(II) ions are connected by two acetate bridges in a syn–syn configuration. The F atoms of the trifluoromethanesulfonate ligands are disordered, with site-occupation factors of 70 and 30. The molecular structure is stabilized by intramolecular face-to-face π–π interactions with centroid–centroid distances in the range 3.5654 (12)–3.8775(12) Å. The crystal structure is stabilized by C—H⋯O interactions, leading to a three-dimensional lattice structure. |
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