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catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]

The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxyl­ato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884253/
https://www.ncbi.nlm.nih.gov/pubmed/24454029
http://dx.doi.org/10.1107/S1600536813026408
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxyl­ato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along [01-1] by carboxylic acid–carbonyl-O bonds. The tetra­hedral coordination of the Li(I) cation is completed by an aqua ligand. The carboxylic acid is involved in an intra-ribbon hydrogen bond. A solvate water molecule showing positional (50:50) disorder is observed. Polymeric ribbons along [01-1] are connected by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional architecture.
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spelling pubmed-38842532014-01-17 catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxyl­ato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along [01-1] by carboxylic acid–carbonyl-O bonds. The tetra­hedral coordination of the Li(I) cation is completed by an aqua ligand. The carboxylic acid is involved in an intra-ribbon hydrogen bond. A solvate water molecule showing positional (50:50) disorder is observed. Polymeric ribbons along [01-1] are connected by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional architecture. International Union of Crystallography 2013-10-12 /pmc/articles/PMC3884253/ /pubmed/24454029 http://dx.doi.org/10.1107/S1600536813026408 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title_full catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title_fullStr catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title_full_unstemmed catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title_short catena-Poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1H-pyrazole-3-carb­oxy­lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
title_sort catena-poly[[di­aqua­bis­(μ(3)-5-carboxyl­ato-1h-pyrazole-3-carb­oxy­lic acid-κ(3) o (3):o (3);o (5))dilithium(i)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884253/
https://www.ncbi.nlm.nih.gov/pubmed/24454029
http://dx.doi.org/10.1107/S1600536813026408
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