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catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate]
The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxylato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884253/ https://www.ncbi.nlm.nih.gov/pubmed/24454029 http://dx.doi.org/10.1107/S1600536813026408 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxylato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along [01-1] by carboxylic acid–carbonyl-O bonds. The tetrahedral coordination of the Li(I) cation is completed by an aqua ligand. The carboxylic acid is involved in an intra-ribbon hydrogen bond. A solvate water molecule showing positional (50:50) disorder is observed. Polymeric ribbons along [01-1] are connected by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional architecture. |
format | Online Article Text |
id | pubmed-3884253 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842532014-01-17 catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The basic structural unit of the title polymeric ribbon, {[Li(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·H(2)O}(n), is a centrosymmetric dinuclear complex in which the two Li(I) ions are bridged by two carboxylato O atoms, to generate a centrosymmetric Li(2)O(2) core. These are connected into a chain along [01-1] by carboxylic acid–carbonyl-O bonds. The tetrahedral coordination of the Li(I) cation is completed by an aqua ligand. The carboxylic acid is involved in an intra-ribbon hydrogen bond. A solvate water molecule showing positional (50:50) disorder is observed. Polymeric ribbons along [01-1] are connected by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional architecture. International Union of Crystallography 2013-10-12 /pmc/articles/PMC3884253/ /pubmed/24454029 http://dx.doi.org/10.1107/S1600536813026408 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate] |
title |
catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3)
O
(3):O
(3);O
(5))dilithium(I)] monohydrate] |
title_full |
catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3)
O
(3):O
(3);O
(5))dilithium(I)] monohydrate] |
title_fullStr |
catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3)
O
(3):O
(3);O
(5))dilithium(I)] monohydrate] |
title_full_unstemmed |
catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3)
O
(3):O
(3);O
(5))dilithium(I)] monohydrate] |
title_short |
catena-Poly[[diaquabis(μ(3)-5-carboxylato-1H-pyrazole-3-carboxylic acid-κ(3)
O
(3):O
(3);O
(5))dilithium(I)] monohydrate] |
title_sort | catena-poly[[diaquabis(μ(3)-5-carboxylato-1h-pyrazole-3-carboxylic acid-κ(3)
o
(3):o
(3);o
(5))dilithium(i)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884253/ https://www.ncbi.nlm.nih.gov/pubmed/24454029 http://dx.doi.org/10.1107/S1600536813026408 |
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