Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate

In the title compound, (C(9)H(8)N)(4)[Te(2)V(8)O(28)]·8H(2)O, the com­plete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H⋯O(p) (p = polyoxidometallate) hydrogen bond and the other an N—H⋯O(w) (w = water) hydrogen bond. The water mol...

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Autores principales: Toumi, Sirine, Toumi, Samah Akriche, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884254/
https://www.ncbi.nlm.nih.gov/pubmed/24454030
http://dx.doi.org/10.1107/S1600536813027347
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author Toumi, Sirine
Toumi, Samah Akriche
Rzaigui, Mohamed
author_facet Toumi, Sirine
Toumi, Samah Akriche
Rzaigui, Mohamed
author_sort Toumi, Sirine
collection PubMed
description In the title compound, (C(9)H(8)N)(4)[Te(2)V(8)O(28)]·8H(2)O, the com­plete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H⋯O(p) (p = polyoxidometallate) hydrogen bond and the other an N—H⋯O(w) (w = water) hydrogen bond. The water mol­ecules further link the components by O—H⋯O(p) and O—H⋯O(w) hydrogen bonds. A number of C—H⋯O inter­actions and aromatic π–π stacking inter­actions [shortest centroid–centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network.
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spelling pubmed-38842542014-01-17 Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate Toumi, Sirine Toumi, Samah Akriche Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(9)H(8)N)(4)[Te(2)V(8)O(28)]·8H(2)O, the com­plete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H⋯O(p) (p = polyoxidometallate) hydrogen bond and the other an N—H⋯O(w) (w = water) hydrogen bond. The water mol­ecules further link the components by O—H⋯O(p) and O—H⋯O(w) hydrogen bonds. A number of C—H⋯O inter­actions and aromatic π–π stacking inter­actions [shortest centroid–centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network. International Union of Crystallography 2013-10-12 /pmc/articles/PMC3884254/ /pubmed/24454030 http://dx.doi.org/10.1107/S1600536813027347 Text en © Toumi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Toumi, Sirine
Toumi, Samah Akriche
Rzaigui, Mohamed
Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title_full Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title_fullStr Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title_full_unstemmed Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title_short Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate
title_sort tetra­quinolinium ditelluro(vi)octa­vanadate(v) octa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884254/
https://www.ncbi.nlm.nih.gov/pubmed/24454030
http://dx.doi.org/10.1107/S1600536813027347
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AT toumisamahakriche tetraquinoliniumditellurovioctavanadatevoctahydrate
AT rzaiguimohamed tetraquinoliniumditellurovioctavanadatevoctahydrate

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