catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]

In the polymeric title compound, [Ba(NO(3))(2)(C(6)H(9)N(3)O(2))(2)](n), the Ba(II) atom is located on a crystallographic twofold axis and is coordinated by ten O atoms. Six are derived from two zwitterionic l-histidine mol­ecules that simultaneously chelate one Ba(II) atom and bridge to another. Th...

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Detalles Bibliográficos
Autores principales: Arularasan, P., Chakkaravarthi, G., Mohan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884255/
https://www.ncbi.nlm.nih.gov/pubmed/24454031
http://dx.doi.org/10.1107/S1600536813027402
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author Arularasan, P.
Chakkaravarthi, G.
Mohan, R.
author_facet Arularasan, P.
Chakkaravarthi, G.
Mohan, R.
author_sort Arularasan, P.
collection PubMed
description In the polymeric title compound, [Ba(NO(3))(2)(C(6)H(9)N(3)O(2))(2)](n), the Ba(II) atom is located on a crystallographic twofold axis and is coordinated by ten O atoms. Six are derived from two zwitterionic l-histidine mol­ecules that simultaneously chelate one Ba(II) atom and bridge to another. The remaining four O atoms are derived from two chelating nitrates. The mol­ecules assemble to form a chain along [010]. In the crystal, chains are linked via N—H⋯O and N—H⋯N hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-38842552014-01-17 catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O] Arularasan, P. Chakkaravarthi, G. Mohan, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [Ba(NO(3))(2)(C(6)H(9)N(3)O(2))(2)](n), the Ba(II) atom is located on a crystallographic twofold axis and is coordinated by ten O atoms. Six are derived from two zwitterionic l-histidine mol­ecules that simultaneously chelate one Ba(II) atom and bridge to another. The remaining four O atoms are derived from two chelating nitrates. The mol­ecules assemble to form a chain along [010]. In the crystal, chains are linked via N—H⋯O and N—H⋯N hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-10-12 /pmc/articles/PMC3884255/ /pubmed/24454031 http://dx.doi.org/10.1107/S1600536813027402 Text en © Arularasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arularasan, P.
Chakkaravarthi, G.
Mohan, R.
catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title_full catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title_fullStr catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title_full_unstemmed catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title_short catena-Poly[[bis­(nitrato-κ(2) O,O′)barium]-bis­(μ-l-histidine-κ(3) O,O′:O]
title_sort catena-poly[[bis­(nitrato-κ(2) o,o′)barium]-bis­(μ-l-histidine-κ(3) o,o′:o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884255/
https://www.ncbi.nlm.nih.gov/pubmed/24454031
http://dx.doi.org/10.1107/S1600536813027402
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