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Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]

In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bi­pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa­hedral geometry. The mo...

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Autores principales: Saravanan, B., Jayamani, A., Sengottuvelan, N., Chakkaravarthi, G., Manivannan, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884256/
https://www.ncbi.nlm.nih.gov/pubmed/24454032
http://dx.doi.org/10.1107/S1600536813027852
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author Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
author_facet Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
author_sort Saravanan, B.
collection PubMed
description In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bi­pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa­hedral geometry. The mol­ecule belongs to the symmetry point group C (2h). The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.8614 (7) Å. The crystal structure exhibits O—H⋯O, C—H⋯O and π–π [centroid–centroid distance = 3.5374 (13) Å] inter­actions.
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spelling pubmed-38842562014-01-17 Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)] Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bi­pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa­hedral geometry. The mol­ecule belongs to the symmetry point group C (2h). The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.8614 (7) Å. The crystal structure exhibits O—H⋯O, C—H⋯O and π–π [centroid–centroid distance = 3.5374 (13) Å] inter­actions. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884256/ /pubmed/24454032 http://dx.doi.org/10.1107/S1600536813027852 Text en © Saravanan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saravanan, B.
Jayamani, A.
Sengottuvelan, N.
Chakkaravarthi, G.
Manivannan, V.
Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title_full Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title_fullStr Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title_full_unstemmed Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title_short Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis­[(2,2′-bi­pyridine-κ(2) N,N′)copper(II)]
title_sort di-μ-hydroxido-κ(4) o:o-di-μ-perchlorato-κ(4) o:o′-bis­[(2,2′-bi­pyridine-κ(2) n,n′)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884256/
https://www.ncbi.nlm.nih.gov/pubmed/24454032
http://dx.doi.org/10.1107/S1600536813027852
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