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Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis[(2,2′-bipyridine-κ(2) N,N′)copper(II)]
In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bipyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octahedral geometry. The mo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884256/ https://www.ncbi.nlm.nih.gov/pubmed/24454032 http://dx.doi.org/10.1107/S1600536813027852 |
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author | Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. |
author_facet | Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. |
author_sort | Saravanan, B. |
collection | PubMed |
description | In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bipyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octahedral geometry. The molecule belongs to the symmetry point group C (2h). The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear molecule, the Cu⋯Cu separation is 2.8614 (7) Å. The crystal structure exhibits O—H⋯O, C—H⋯O and π–π [centroid–centroid distance = 3.5374 (13) Å] interactions. |
format | Online Article Text |
id | pubmed-3884256 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842562014-01-17 Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis[(2,2′-bipyridine-κ(2) N,N′)copper(II)] Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear copper(II) complex, [Cu(2)(ClO(4))(2)(OH)(2)(C(10)H(8)N(2))(2)], the Cu(II) ion is coordinated in the form of a Jahn–Teller distorted octahedron by two bipyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octahedral geometry. The molecule belongs to the symmetry point group C (2h). The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear molecule, the Cu⋯Cu separation is 2.8614 (7) Å. The crystal structure exhibits O—H⋯O, C—H⋯O and π–π [centroid–centroid distance = 3.5374 (13) Å] interactions. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884256/ /pubmed/24454032 http://dx.doi.org/10.1107/S1600536813027852 Text en © Saravanan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Saravanan, B. Jayamani, A. Sengottuvelan, N. Chakkaravarthi, G. Manivannan, V. Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O′-bis[(2,2′-bipyridine-κ(2) N,N′)copper(II)] |
title | Di-μ-hydroxido-κ(4)
O:O-di-μ-perchlorato-κ(4)
O:O′-bis[(2,2′-bipyridine-κ(2)
N,N′)copper(II)] |
title_full | Di-μ-hydroxido-κ(4)
O:O-di-μ-perchlorato-κ(4)
O:O′-bis[(2,2′-bipyridine-κ(2)
N,N′)copper(II)] |
title_fullStr | Di-μ-hydroxido-κ(4)
O:O-di-μ-perchlorato-κ(4)
O:O′-bis[(2,2′-bipyridine-κ(2)
N,N′)copper(II)] |
title_full_unstemmed | Di-μ-hydroxido-κ(4)
O:O-di-μ-perchlorato-κ(4)
O:O′-bis[(2,2′-bipyridine-κ(2)
N,N′)copper(II)] |
title_short | Di-μ-hydroxido-κ(4)
O:O-di-μ-perchlorato-κ(4)
O:O′-bis[(2,2′-bipyridine-κ(2)
N,N′)copper(II)] |
title_sort | di-μ-hydroxido-κ(4)
o:o-di-μ-perchlorato-κ(4)
o:o′-bis[(2,2′-bipyridine-κ(2)
n,n′)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884256/ https://www.ncbi.nlm.nih.gov/pubmed/24454032 http://dx.doi.org/10.1107/S1600536813027852 |
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