Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)

In the title compound, [Co(C(8)H(7)BrNO)(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2)...

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Detalles Bibliográficos
Autores principales: Huang, Qiu-Ping, Zhang, Chun-Lian, Zhao, Ru-Xia, Yang, Li, Jiang, Xi-Fu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884257/
https://www.ncbi.nlm.nih.gov/pubmed/24454033
http://dx.doi.org/10.1107/S1600536813027591
Descripción
Sumario:In the title compound, [Co(C(8)H(7)BrNO)(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Br hydrogen bonds, forming inversion dimers.

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