Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)

In the title compound, [Co(C(8)H(7)BrNO)(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2)...

Descripción completa

Detalles Bibliográficos
Autores principales: Huang, Qiu-Ping, Zhang, Chun-Lian, Zhao, Ru-Xia, Yang, Li, Jiang, Xi-Fu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884257/
https://www.ncbi.nlm.nih.gov/pubmed/24454033
http://dx.doi.org/10.1107/S1600536813027591
_version_ 1782298548040105984
author Huang, Qiu-Ping
Zhang, Chun-Lian
Zhao, Ru-Xia
Yang, Li
Jiang, Xi-Fu
author_facet Huang, Qiu-Ping
Zhang, Chun-Lian
Zhao, Ru-Xia
Yang, Li
Jiang, Xi-Fu
author_sort Huang, Qiu-Ping
collection PubMed
description In the title compound, [Co(C(8)H(7)BrNO)(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Br hydrogen bonds, forming inversion dimers.
format Online
Article
Text
id pubmed-3884257
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38842572014-01-17 Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III) Huang, Qiu-Ping Zhang, Chun-Lian Zhao, Ru-Xia Yang, Li Jiang, Xi-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(7)BrNO)(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Br hydrogen bonds, forming inversion dimers. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884257/ /pubmed/24454033 http://dx.doi.org/10.1107/S1600536813027591 Text en © Huang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Qiu-Ping
Zhang, Chun-Lian
Zhao, Ru-Xia
Yang, Li
Jiang, Xi-Fu
Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title_full Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title_fullStr Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title_full_unstemmed Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title_short Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) N,O]cobalt(III)
title_sort tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-κ(2) n,o]cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884257/
https://www.ncbi.nlm.nih.gov/pubmed/24454033
http://dx.doi.org/10.1107/S1600536813027591
work_keys_str_mv AT huangqiuping tris4bromo2methyliminomethylphenolatok2nocobaltiii
AT zhangchunlian tris4bromo2methyliminomethylphenolatok2nocobaltiii
AT zhaoruxia tris4bromo2methyliminomethylphenolatok2nocobaltiii
AT yangli tris4bromo2methyliminomethylphenolatok2nocobaltiii
AT jiangxifu tris4bromo2methyliminomethylphenolatok2nocobaltiii

Ejemplares similares