Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)

The title compound, [Co(2){P(C(6)H(5))(2)}(2)(C(3)H(9)P)(4)], was obtained by the addition of di­phenyl­phosphane to a solution of Co(CH(3))(C(3)H(9)P)(4). The dinuclear complex mol­ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co—Co dista...

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Detalles Bibliográficos
Autores principales: Beck, Robert, Klein, Hans-Friedrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884259/
https://www.ncbi.nlm.nih.gov/pubmed/24454035
http://dx.doi.org/10.1107/S1600536813027384
Descripción
Sumario:The title compound, [Co(2){P(C(6)H(5))(2)}(2)(C(3)H(9)P)(4)], was obtained by the addition of di­phenyl­phosphane to a solution of Co(CH(3))(C(3)H(9)P)(4). The dinuclear complex mol­ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co—Co distance of 2.3670 (8) Å lies within the range of metal–metal double bonds. As a result of inversion symmetry, the four-membered Co(2)P(2) core is rigorously planar, and the two bridging P(C(6)H(5))(2)-ligands and the terminal C(3)H(9)P ligands are arranged in a pseudo-tetra­hedral fashion about the Co(I) atom.

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