Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)

The title compound, [Co(2){P(C(6)H(5))(2)}(2)(C(3)H(9)P)(4)], was obtained by the addition of di­phenyl­phosphane to a solution of Co(CH(3))(C(3)H(9)P)(4). The dinuclear complex mol­ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co—Co dista...

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Detalles Bibliográficos
Autores principales: Beck, Robert, Klein, Hans-Friedrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884259/
https://www.ncbi.nlm.nih.gov/pubmed/24454035
http://dx.doi.org/10.1107/S1600536813027384
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author Beck, Robert
Klein, Hans-Friedrich
author_facet Beck, Robert
Klein, Hans-Friedrich
author_sort Beck, Robert
collection PubMed
description The title compound, [Co(2){P(C(6)H(5))(2)}(2)(C(3)H(9)P)(4)], was obtained by the addition of di­phenyl­phosphane to a solution of Co(CH(3))(C(3)H(9)P)(4). The dinuclear complex mol­ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co—Co distance of 2.3670 (8) Å lies within the range of metal–metal double bonds. As a result of inversion symmetry, the four-membered Co(2)P(2) core is rigorously planar, and the two bridging P(C(6)H(5))(2)-ligands and the terminal C(3)H(9)P ligands are arranged in a pseudo-tetra­hedral fashion about the Co(I) atom.
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spelling pubmed-38842592014-01-17 Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co) Beck, Robert Klein, Hans-Friedrich Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(2){P(C(6)H(5))(2)}(2)(C(3)H(9)P)(4)], was obtained by the addition of di­phenyl­phosphane to a solution of Co(CH(3))(C(3)H(9)P)(4). The dinuclear complex mol­ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co—Co distance of 2.3670 (8) Å lies within the range of metal–metal double bonds. As a result of inversion symmetry, the four-membered Co(2)P(2) core is rigorously planar, and the two bridging P(C(6)H(5))(2)-ligands and the terminal C(3)H(9)P ligands are arranged in a pseudo-tetra­hedral fashion about the Co(I) atom. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884259/ /pubmed/24454035 http://dx.doi.org/10.1107/S1600536813027384 Text en © Beck and Klein 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Beck, Robert
Klein, Hans-Friedrich
Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title_full Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title_fullStr Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title_full_unstemmed Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title_short Bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(I)](Co—Co)
title_sort bis(μ-di­phenyl­phosphan­yl)bis­[(tri­methyl­phosphane)cobalt(i)](co—co)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884259/
https://www.ncbi.nlm.nih.gov/pubmed/24454035
http://dx.doi.org/10.1107/S1600536813027384
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