[1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate

In the title compound, [CoRu(C(5)H(5))(C(16)H(9))(C(17)H(14)P)(2)]PF(6), the Ru(II) atom is coordinated by a cyclo­penta­dienyl ring in an η(5)-mode, one C atom from a 4,4′-diethynyl-1,1′-biphenyl ligand and two P atoms from a chelating 1,1′-bis­(di­phenyl­phosphan­yl)cobaltocenium ligand, giving a...

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Detalles Bibliográficos
Autores principales: Zeng, Ling-Zhen, Wu, Yun-Ying, Tian, Guang-Xuan, Li, Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884261/
https://www.ncbi.nlm.nih.gov/pubmed/24454037
http://dx.doi.org/10.1107/S1600536813028195
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author Zeng, Ling-Zhen
Wu, Yun-Ying
Tian, Guang-Xuan
Li, Zhen
author_facet Zeng, Ling-Zhen
Wu, Yun-Ying
Tian, Guang-Xuan
Li, Zhen
author_sort Zeng, Ling-Zhen
collection PubMed
description In the title compound, [CoRu(C(5)H(5))(C(16)H(9))(C(17)H(14)P)(2)]PF(6), the Ru(II) atom is coordinated by a cyclo­penta­dienyl ring in an η(5)-mode, one C atom from a 4,4′-diethynyl-1,1′-biphenyl ligand and two P atoms from a chelating 1,1′-bis­(di­phenyl­phosphan­yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C—H⋯F hydrogen bonds link the complex cations and hexa­fluorido­phosphate anions into a three-dimensional supra­molecular structure.
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spelling pubmed-38842612014-01-17 [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate Zeng, Ling-Zhen Wu, Yun-Ying Tian, Guang-Xuan Li, Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoRu(C(5)H(5))(C(16)H(9))(C(17)H(14)P)(2)]PF(6), the Ru(II) atom is coordinated by a cyclo­penta­dienyl ring in an η(5)-mode, one C atom from a 4,4′-diethynyl-1,1′-biphenyl ligand and two P atoms from a chelating 1,1′-bis­(di­phenyl­phosphan­yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C—H⋯F hydrogen bonds link the complex cations and hexa­fluorido­phosphate anions into a three-dimensional supra­molecular structure. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884261/ /pubmed/24454037 http://dx.doi.org/10.1107/S1600536813028195 Text en © Zeng et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeng, Ling-Zhen
Wu, Yun-Ying
Tian, Guang-Xuan
Li, Zhen
[1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title_full [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title_fullStr [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title_short [1,1′-Bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) P,P′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κC}ruthenium(II) hexa­fluorido­phosphate
title_sort [1,1′-bis(di­phenyl­phosphan­yl)cobalto­cenium-κ(2) p,p′](η(5)-cyclo­penta­dien­yl){2-[4-(4-ethynylphen­yl)phen­yl]ethynyl-κc}ruthenium(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884261/
https://www.ncbi.nlm.nih.gov/pubmed/24454037
http://dx.doi.org/10.1107/S1600536813028195
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