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catena-Poly[2-methylpyridinium [tungstate-di-μ-selenido-silver-di-μ-selenido] 2-methylpyridine monosolvate]
The title compound, {(C(6)H(8)N)[AgWSe(4)]·C(6)H(7)N}(n), consists of anionic [WAgSe(4)](n) chains, 2-methylpyridinium cations and neutral 2-methylpyridine molecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms ar...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884262/ https://www.ncbi.nlm.nih.gov/pubmed/24454038 http://dx.doi.org/10.1107/S1600536813028213 |
Sumario: | The title compound, {(C(6)H(8)N)[AgWSe(4)]·C(6)H(7)N}(n), consists of anionic [WAgSe(4)](n) chains, 2-methylpyridinium cations and neutral 2-methylpyridine molecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms are located on a twofold rotation axis and each metal atom is coordinated by four Se atoms in distorted tetrahedral geometry. In the crystal, the 2-methylpyridinium cation and 2-methylpyridine molecule are linked via N—H⋯N hydrogen bonding. Weak C—H⋯Se interactions link the organic components and polymeric anions into a three-dimensional architecture. |
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