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catena-Poly[2-methyl­pyridinium [tungstate-di-μ-selenido-silver-di-μ-selenido] 2-methyl­pyridine monosolvate]

The title compound, {(C(6)H(8)N)[AgWSe(4)]·C(6)H(7)N}(n), consists of anionic [WAgSe(4)](n) chains, 2-methyl­pyridinium cations and neutral 2-methyl­pyridine mol­ecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms ar...

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Detalles Bibliográficos
Autores principales: Zhou, Lu-Jun, Shi, Hua-Tian, Xu, Chao, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884262/
https://www.ncbi.nlm.nih.gov/pubmed/24454038
http://dx.doi.org/10.1107/S1600536813028213
Descripción
Sumario:The title compound, {(C(6)H(8)N)[AgWSe(4)]·C(6)H(7)N}(n), consists of anionic [WAgSe(4)](n) chains, 2-methyl­pyridinium cations and neutral 2-methyl­pyridine mol­ecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms are located on a twofold rotation axis and each metal atom is coordinated by four Se atoms in distorted tetra­hedral geometry. In the crystal, the 2-methyl­pyridinium cation and 2-methyl­pyridine mol­ecule are linked via N—H⋯N hydrogen bonding. Weak C—H⋯Se inter­actions link the organic components and polymeric anions into a three-dimensional architecture.