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(2,2′-Bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II)
In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2))], the Cu(II) cation is chelated by two nitrate anions and by one 2,2′-bipyridine ligand in a distorted N(2)O(4) octahedral geometry. The dihedral angle between the pyridine rings is 1.92 (11)°. In the crystal, π–π stacking between parallel pyridin...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884263/ https://www.ncbi.nlm.nih.gov/pubmed/24454039 http://dx.doi.org/10.1107/S1600536813028201 |
| _version_ | 1782298549434712064 |
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| author | Liu, Feng-Yi Zhang, Ming-Hui Kou, Jun-Feng |
| author_facet | Liu, Feng-Yi Zhang, Ming-Hui Kou, Jun-Feng |
| author_sort | Liu, Feng-Yi |
| collection | PubMed |
| description | In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2))], the Cu(II) cation is chelated by two nitrate anions and by one 2,2′-bipyridine ligand in a distorted N(2)O(4) octahedral geometry. The dihedral angle between the pyridine rings is 1.92 (11)°. In the crystal, π–π stacking between parallel pyridine rings of adjacent complex molecules is observed, the centroid–centroid distance being 3.6788 (19) Å. Weak C—H⋯O hydrogen bonds further link the molecules into a three-dimensional supramolecular architecture. |
| format | Online Article Text |
| id | pubmed-3884263 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38842632014-01-17 (2,2′-Bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II) Liu, Feng-Yi Zhang, Ming-Hui Kou, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2))], the Cu(II) cation is chelated by two nitrate anions and by one 2,2′-bipyridine ligand in a distorted N(2)O(4) octahedral geometry. The dihedral angle between the pyridine rings is 1.92 (11)°. In the crystal, π–π stacking between parallel pyridine rings of adjacent complex molecules is observed, the centroid–centroid distance being 3.6788 (19) Å. Weak C—H⋯O hydrogen bonds further link the molecules into a three-dimensional supramolecular architecture. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884263/ /pubmed/24454039 http://dx.doi.org/10.1107/S1600536813028201 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Feng-Yi Zhang, Ming-Hui Kou, Jun-Feng (2,2′-Bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II) |
| title | (2,2′-Bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)bis(nitrato-κ(2)
o,o′)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884263/ https://www.ncbi.nlm.nih.gov/pubmed/24454039 http://dx.doi.org/10.1107/S1600536813028201 |
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