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Rubidium pentaaqua(l-serine)cobalt(II) hexahydrogenhexamolybdocobaltate(III) l-serine monosolvate decahydrate
The Co(2+) ion in the title compound, Rb[Co(C(3)H(7)NO(3))(H(2)O)(5)][H(6)CoMo(6)O(24)]·C(3)H(7)NO(3)·10H(2)O, is coordinated by five water molecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884265/ https://www.ncbi.nlm.nih.gov/pubmed/24454041 http://dx.doi.org/10.1107/S1600536813028304 |
| Sumario: | The Co(2+) ion in the title compound, Rb[Co(C(3)H(7)NO(3))(H(2)O)(5)][H(6)CoMo(6)O(24)]·C(3)H(7)NO(3)·10H(2)O, is coordinated by five water molecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H(6)Co(III)Mo(6)O(24)](3−) polyanions are stacked along the b-axis direction, mediated by bridging Rb—O bonds. N—H⋯O and O—H⋯O hydrogen bonds are observed involving the l-serine molecules. |
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