Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate

The Co(2+) ion in the title compound, Rb[Co(C(3)H(7)NO(3))(H(2)O)(5)][H(6)CoMo(6)O(24)]·C(3)H(7)NO(3)·10H(2)O, is coordinated by five water mol­ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Iijima, Jun, Naruke, Haruo, Takiyama, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884265/
https://www.ncbi.nlm.nih.gov/pubmed/24454041
http://dx.doi.org/10.1107/S1600536813028304
_version_ 1782298549891891200
author Iijima, Jun
Naruke, Haruo
Takiyama, Hiroshi
author_facet Iijima, Jun
Naruke, Haruo
Takiyama, Hiroshi
author_sort Iijima, Jun
collection PubMed
description The Co(2+) ion in the title compound, Rb[Co(C(3)H(7)NO(3))(H(2)O)(5)][H(6)CoMo(6)O(24)]·C(3)H(7)NO(3)·10H(2)O, is coordinated by five water mol­ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H(6)Co(III)Mo(6)O(24)](3−) polyanions are stacked along the b-axis direction, mediated by bridging Rb—O bonds. N—H⋯O and O—H⋯O hydrogen bonds are observed involving the l-serine mol­ecules.
format Online
Article
Text
id pubmed-3884265
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38842652014-01-17 Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate Iijima, Jun Naruke, Haruo Takiyama, Hiroshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(2+) ion in the title compound, Rb[Co(C(3)H(7)NO(3))(H(2)O)(5)][H(6)CoMo(6)O(24)]·C(3)H(7)NO(3)·10H(2)O, is coordinated by five water mol­ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H(6)Co(III)Mo(6)O(24)](3−) polyanions are stacked along the b-axis direction, mediated by bridging Rb—O bonds. N—H⋯O and O—H⋯O hydrogen bonds are observed involving the l-serine mol­ecules. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884265/ /pubmed/24454041 http://dx.doi.org/10.1107/S1600536813028304 Text en © Iijima et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Iijima, Jun
Naruke, Haruo
Takiyama, Hiroshi
Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title_full Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title_fullStr Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title_full_unstemmed Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title_short Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate
title_sort rubidium penta­aqua­(l-serine)cobalt(ii) hexa­hydrogenhexa­molybdocobaltate(iii) l-serine monosolvate deca­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884265/
https://www.ncbi.nlm.nih.gov/pubmed/24454041
http://dx.doi.org/10.1107/S1600536813028304
work_keys_str_mv AT iijimajun rubidiumpentaaqualserinecobaltiihexahydrogenhexamolybdocobaltateiiilserinemonosolvatedecahydrate
AT narukeharuo rubidiumpentaaqualserinecobaltiihexahydrogenhexamolybdocobaltateiiilserinemonosolvatedecahydrate
AT takiyamahiroshi rubidiumpentaaqualserinecobaltiihexahydrogenhexamolybdocobaltateiiilserinemonosolvatedecahydrate

Ejemplares similares