Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)

In the crystal structure of the title compound, (C(3)H(11)NOP)(2)[PdCl(4)], (di­methyl­phosphor­yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N—H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl(4)](2−) counter-dianion is located about a c...

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Detalles Bibliográficos
Autor principal: Reiss, Guido J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884266/
https://www.ncbi.nlm.nih.gov/pubmed/24454042
http://dx.doi.org/10.1107/S1600536813028067
Descripción
Sumario:In the crystal structure of the title compound, (C(3)H(11)NOP)(2)[PdCl(4)], (di­methyl­phosphor­yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N—H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl(4)](2−) counter-dianion is located about a center of inversion. The dications and the [PdCl(4)](2−) dianions are connected by medium–strong N—H⋯Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N—H⋯Cl hydrogen bonds connect the chains into a three-dimensional network.

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