Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)

In the crystal structure of the title compound, (C(3)H(11)NOP)(2)[PdCl(4)], (di­methyl­phosphor­yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N—H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl(4)](2−) counter-dianion is located about a c...

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Detalles Bibliográficos
Autor principal: Reiss, Guido J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884266/
https://www.ncbi.nlm.nih.gov/pubmed/24454042
http://dx.doi.org/10.1107/S1600536813028067
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author Reiss, Guido J.
author_facet Reiss, Guido J.
author_sort Reiss, Guido J.
collection PubMed
description In the crystal structure of the title compound, (C(3)H(11)NOP)(2)[PdCl(4)], (di­methyl­phosphor­yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N—H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl(4)](2−) counter-dianion is located about a center of inversion. The dications and the [PdCl(4)](2−) dianions are connected by medium–strong N—H⋯Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N—H⋯Cl hydrogen bonds connect the chains into a three-dimensional network.
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spelling pubmed-38842662014-01-17 Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II) Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(3)H(11)NOP)(2)[PdCl(4)], (di­methyl­phosphor­yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N—H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl(4)](2−) counter-dianion is located about a center of inversion. The dications and the [PdCl(4)](2−) dianions are connected by medium–strong N—H⋯Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N—H⋯Cl hydrogen bonds connect the chains into a three-dimensional network. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884266/ /pubmed/24454042 http://dx.doi.org/10.1107/S1600536813028067 Text en © Guido J. Reiss 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reiss, Guido J.
Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title_full Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title_fullStr Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title_full_unstemmed Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title_short Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)
title_sort bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884266/
https://www.ncbi.nlm.nih.gov/pubmed/24454042
http://dx.doi.org/10.1107/S1600536813028067
work_keys_str_mv AT reissguidoj bisdimethylphosphorylmethanaminiumtetrachloridopalladateii

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