Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide

The title compound, [Zn{(CH(3))(2)SO}(6)]I(4), is a one-dimensional supra­molecular polymer along a threefold rotation axis of the space group. It is built up from discrete [Zn{(CH(3))(2)SO}(6)](2+) units connected through non-classical hydrogen bonds to linear I(4) (2−) polyiodide anions (C—H⋯I = 3...

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Autores principales: Garzón-Tovar, Luis, Duarte-Ruiz, Álvaro, Fanwick, Phillip E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884268/
https://www.ncbi.nlm.nih.gov/pubmed/24454044
http://dx.doi.org/10.1107/S1600536813028377
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author Garzón-Tovar, Luis
Duarte-Ruiz, Álvaro
Fanwick, Phillip E.
author_facet Garzón-Tovar, Luis
Duarte-Ruiz, Álvaro
Fanwick, Phillip E.
author_sort Garzón-Tovar, Luis
collection PubMed
description The title compound, [Zn{(CH(3))(2)SO}(6)]I(4), is a one-dimensional supra­molecular polymer along a threefold rotation axis of the space group. It is built up from discrete [Zn{(CH(3))(2)SO}(6)](2+) units connected through non-classical hydrogen bonds to linear I(4) (2−) polyiodide anions (C—H⋯I = 3.168 Å). The Zn(II) ion in the cation has an octa­hedral coordination geometry, with all six Zn—O bond lengths being equivalent, at 2.111 (4) Å. The linear polyiodide anion contains a neutral I(2) mol­ecule weakly coordinated to two iodide ions.
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spelling pubmed-38842682014-01-17 Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide Garzón-Tovar, Luis Duarte-Ruiz, Álvaro Fanwick, Phillip E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn{(CH(3))(2)SO}(6)]I(4), is a one-dimensional supra­molecular polymer along a threefold rotation axis of the space group. It is built up from discrete [Zn{(CH(3))(2)SO}(6)](2+) units connected through non-classical hydrogen bonds to linear I(4) (2−) polyiodide anions (C—H⋯I = 3.168 Å). The Zn(II) ion in the cation has an octa­hedral coordination geometry, with all six Zn—O bond lengths being equivalent, at 2.111 (4) Å. The linear polyiodide anion contains a neutral I(2) mol­ecule weakly coordinated to two iodide ions. International Union of Crystallography 2013-10-23 /pmc/articles/PMC3884268/ /pubmed/24454044 http://dx.doi.org/10.1107/S1600536813028377 Text en © Garzón-Tovar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Garzón-Tovar, Luis
Duarte-Ruiz, Álvaro
Fanwick, Phillip E.
Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title_full Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title_fullStr Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title_full_unstemmed Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title_short Hexa­kis­(dimethyl sulfoxide-κO)zinc(II) poly­iodide
title_sort hexa­kis­(dimethyl sulfoxide-κo)zinc(ii) poly­iodide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884268/
https://www.ncbi.nlm.nih.gov/pubmed/24454044
http://dx.doi.org/10.1107/S1600536813028377
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AT duarteruizalvaro hexakisdimethylsulfoxidekozinciipolyiodide
AT fanwickphillipe hexakisdimethylsulfoxidekozinciipolyiodide

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