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Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN (3)]copper(II)
In the title complex, [CuCl(2)(C(12)H(14)N(2))(2)], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedr...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884270/ https://www.ncbi.nlm.nih.gov/pubmed/24454046 http://dx.doi.org/10.1107/S1600536813028821 |
| Sumario: | In the title complex, [CuCl(2)(C(12)H(14)N(2))(2)], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99 (18)°. Weak intramolecular C—H⋯Cl hydrogen-bonding interactions consolidate the molecular conformation. |
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