Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)

In the title complex, [CuCl(2)(C(12)H(14)N(2))(2)], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedr...

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Detalles Bibliográficos
Autores principales: Zhang, Yantao, Lin, Zhuzhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884270/
https://www.ncbi.nlm.nih.gov/pubmed/24454046
http://dx.doi.org/10.1107/S1600536813028821
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author Zhang, Yantao
Lin, Zhuzhen
author_facet Zhang, Yantao
Lin, Zhuzhen
author_sort Zhang, Yantao
collection PubMed
description In the title complex, [CuCl(2)(C(12)H(14)N(2))(2)], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99 (18)°. Weak intra­molecular C—H⋯Cl hydrogen-bonding inter­actions consolidate the mol­ecular conformation.
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spelling pubmed-38842702014-01-17 Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II) Zhang, Yantao Lin, Zhuzhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(12)H(14)N(2))(2)], the Cu(2+) cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99 (18)°. Weak intra­molecular C—H⋯Cl hydrogen-bonding inter­actions consolidate the mol­ecular conformation. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884270/ /pubmed/24454046 http://dx.doi.org/10.1107/S1600536813028821 Text en © Zhang and Lin 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yantao
Lin, Zhuzhen
Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title_full Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title_fullStr Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title_full_unstemmed Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title_short Di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1H-imidazole-κN (3)]copper(II)
title_sort di­chlorido­bis­[1-(2,4,6-tri­methyl­phen­yl)-1h-imidazole-κn (3)]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884270/
https://www.ncbi.nlm.nih.gov/pubmed/24454046
http://dx.doi.org/10.1107/S1600536813028821
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AT linzhuzhen dichloridobis1246trimethylphenyl1himidazolekn3copperii

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