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Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)

The complete binuclear molecule of the title compound, [Cd(2)I(4)(C(14)H(12)N(2)O(2))(2)], is generated by the application of a centre of inversion. The Cd—I bond lengths of the central core are close and uniformly longer than the exocyclic Cd—I bond. The coordination sphere of the Cd(II) atom is co...

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Detalles Bibliográficos
Autores principales: Basu Baul, Tushar S., Kundu, Sajal, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884272/
https://www.ncbi.nlm.nih.gov/pubmed/24454048
http://dx.doi.org/10.1107/S160053681302905X
Descripción
Sumario:The complete binuclear molecule of the title compound, [Cd(2)I(4)(C(14)H(12)N(2)O(2))(2)], is generated by the application of a centre of inversion. The Cd—I bond lengths of the central core are close and uniformly longer than the exocyclic Cd—I bond. The coordination sphere of the Cd(II) atom is completed by two N atoms of a chelating methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate ligand, and is based on a square pyramid with the terminal I atom in the apical position. The three-dimensional crystal packing is stabilized by C—H⋯O and C—H⋯π inter­actions, each involving the pyridine ring.