Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)

The complete binuclear molecule of the title compound, [Cd(2)I(4)(C(14)H(12)N(2)O(2))(2)], is generated by the application of a centre of inversion. The Cd—I bond lengths of the central core are close and uniformly longer than the exocyclic Cd—I bond. The coordination sphere of the Cd(II) atom is co...

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Autores principales: Basu Baul, Tushar S., Kundu, Sajal, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884272/
https://www.ncbi.nlm.nih.gov/pubmed/24454048
http://dx.doi.org/10.1107/S160053681302905X
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author Basu Baul, Tushar S.
Kundu, Sajal
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Basu Baul, Tushar S.
Kundu, Sajal
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Basu Baul, Tushar S.
collection PubMed
description The complete binuclear molecule of the title compound, [Cd(2)I(4)(C(14)H(12)N(2)O(2))(2)], is generated by the application of a centre of inversion. The Cd—I bond lengths of the central core are close and uniformly longer than the exocyclic Cd—I bond. The coordination sphere of the Cd(II) atom is completed by two N atoms of a chelating methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate ligand, and is based on a square pyramid with the terminal I atom in the apical position. The three-dimensional crystal packing is stabilized by C—H⋯O and C—H⋯π inter­actions, each involving the pyridine ring.
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spelling pubmed-38842722014-01-17 Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium) Basu Baul, Tushar S. Kundu, Sajal Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete binuclear molecule of the title compound, [Cd(2)I(4)(C(14)H(12)N(2)O(2))(2)], is generated by the application of a centre of inversion. The Cd—I bond lengths of the central core are close and uniformly longer than the exocyclic Cd—I bond. The coordination sphere of the Cd(II) atom is completed by two N atoms of a chelating methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate ligand, and is based on a square pyramid with the terminal I atom in the apical position. The three-dimensional crystal packing is stabilized by C—H⋯O and C—H⋯π inter­actions, each involving the pyridine ring. International Union of Crystallography 2013-10-31 /pmc/articles/PMC3884272/ /pubmed/24454048 http://dx.doi.org/10.1107/S160053681302905X Text en © Basu Baul et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Basu Baul, Tushar S.
Kundu, Sajal
Ng, Seik Weng
Tiekink, Edward R. T.
Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title_full Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title_fullStr Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title_full_unstemmed Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title_short Di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) N,N′}cadmium)
title_sort di-μ-iodido-bis­(iodido­{methyl 4-[(pyridin-2-yl­methyl­idene)amino]­benzoate-κ(2) n,n′}cadmium)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884272/
https://www.ncbi.nlm.nih.gov/pubmed/24454048
http://dx.doi.org/10.1107/S160053681302905X
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AT ngseikweng dimiodidobisiodidomethyl4pyridin2ylmethylideneaminobenzoatek2nncadmium
AT tiekinkedwardrt dimiodidobisiodidomethyl4pyridin2ylmethylideneaminobenzoatek2nncadmium

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