Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate

The complete binuclear complex in [Fe(2)(C(7)H(4)NO(4))(4)(OH)(2)]·2H(2)O, is generated by the application twofold symmetry. The Fe(III) atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-di­carboxyl­ato ligands, forming a distorted...

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Detalles Bibliográficos
Autor principal: Cao, Wenhai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884273/
https://www.ncbi.nlm.nih.gov/pubmed/24454049
http://dx.doi.org/10.1107/S1600536813029449
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author Cao, Wenhai
author_facet Cao, Wenhai
author_sort Cao, Wenhai
collection PubMed
description The complete binuclear complex in [Fe(2)(C(7)H(4)NO(4))(4)(OH)(2)]·2H(2)O, is generated by the application twofold symmetry. The Fe(III) atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-di­carboxyl­ato ligands, forming a distorted octa­hedral geometry. The Fe⋯Fe separation within the dinuclear complex is 3.0657 (4) Å. In the crystal, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions connect the mol­ecules into a three-dimensional supra­molecular network.
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spelling pubmed-38842732014-01-17 Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate Cao, Wenhai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete binuclear complex in [Fe(2)(C(7)H(4)NO(4))(4)(OH)(2)]·2H(2)O, is generated by the application twofold symmetry. The Fe(III) atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-di­carboxyl­ato ligands, forming a distorted octa­hedral geometry. The Fe⋯Fe separation within the dinuclear complex is 3.0657 (4) Å. In the crystal, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions connect the mol­ecules into a three-dimensional supra­molecular network. International Union of Crystallography 2013-10-31 /pmc/articles/PMC3884273/ /pubmed/24454049 http://dx.doi.org/10.1107/S1600536813029449 Text en © Wenhai Cao 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Wenhai
Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title_full Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title_fullStr Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title_full_unstemmed Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title_short Bis(μ-hydroxido-κ(2) O:O)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))iron(III)] dihydrate
title_sort bis(μ-hydroxido-κ(2) o:o)bis[bis(5-car­boxy­pyridine-2-carboxyl­ato-κ(2) n,o (2))iron(iii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884273/
https://www.ncbi.nlm.nih.gov/pubmed/24454049
http://dx.doi.org/10.1107/S1600536813029449
work_keys_str_mv AT caowenhai bismhydroxidok2oobisbis5carboxypyridine2carboxylatok2no2ironiiidihydrate

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