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Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate
In the title compound, [Ti(2)(C(16)H(14)N(2)O(2))(2)O(2)]·2CHCl(3), the Ti(IV) atom in the centrosymmetric complex has a distorted octahedral N(2)O(4) coordination environment and is linked via two μ(2)-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884274/ https://www.ncbi.nlm.nih.gov/pubmed/24454050 http://dx.doi.org/10.1107/S1600536813029371 |
Sumario: | In the title compound, [Ti(2)(C(16)H(14)N(2)O(2))(2)O(2)]·2CHCl(3), the Ti(IV) atom in the centrosymmetric complex has a distorted octahedral N(2)O(4) coordination environment and is linked via two μ(2)-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N′-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to [100], forming channels in which the solvent chloroform molecules are located. C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. |
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