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Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate
In the title compound, [Ti(2)(C(16)H(14)N(2)O(2))(2)O(2)]·2CHCl(3), the Ti(IV) atom in the centrosymmetric complex has a distorted octahedral N(2)O(4) coordination environment and is linked via two μ(2)-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884274/ https://www.ncbi.nlm.nih.gov/pubmed/24454050 http://dx.doi.org/10.1107/S1600536813029371 |
| _version_ | 1782298552071880704 |
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| author | Zaitsev, Kirill V. Karlov, Sergey S. Zaitseva, Galina S. Lermontova, Elmira Kh. Churakov, Andrei V. |
| author_facet | Zaitsev, Kirill V. Karlov, Sergey S. Zaitseva, Galina S. Lermontova, Elmira Kh. Churakov, Andrei V. |
| author_sort | Zaitsev, Kirill V. |
| collection | PubMed |
| description | In the title compound, [Ti(2)(C(16)H(14)N(2)O(2))(2)O(2)]·2CHCl(3), the Ti(IV) atom in the centrosymmetric complex has a distorted octahedral N(2)O(4) coordination environment and is linked via two μ(2)-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N′-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to [100], forming channels in which the solvent chloroform molecules are located. C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. |
| format | Online Article Text |
| id | pubmed-3884274 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38842742014-01-17 Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate Zaitsev, Kirill V. Karlov, Sergey S. Zaitseva, Galina S. Lermontova, Elmira Kh. Churakov, Andrei V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ti(2)(C(16)H(14)N(2)O(2))(2)O(2)]·2CHCl(3), the Ti(IV) atom in the centrosymmetric complex has a distorted octahedral N(2)O(4) coordination environment and is linked via two μ(2)-oxido bridges into a dinuclear centrosymmetric complex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N′-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to [100], forming channels in which the solvent chloroform molecules are located. C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. International Union of Crystallography 2013-10-31 /pmc/articles/PMC3884274/ /pubmed/24454050 http://dx.doi.org/10.1107/S1600536813029371 Text en © Zaitsev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zaitsev, Kirill V. Karlov, Sergey S. Zaitseva, Galina S. Lermontova, Elmira Kh. Churakov, Andrei V. Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_full | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_fullStr | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_full_unstemmed | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_short | Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate |
| title_sort | di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(iv)) chloroform disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884274/ https://www.ncbi.nlm.nih.gov/pubmed/24454050 http://dx.doi.org/10.1107/S1600536813029371 |
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