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Anthracene-1,4,9,10-tetra­one

The asymmetric unit of the title compound, C(14)H(6)O(4), contains three independent mol­ecules (A, B and C). In mol­ecule C, there are two disordered sets of two carbonyl O atoms [occupancies = 0.643 (11) and 0.357 (11)]. All three mol­ecules are non-planar due to repulsion between two O atoms in p...

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Detalles Bibliográficos
Autores principales: Kitamura, Chitoshi, Kawase, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884275/
https://www.ncbi.nlm.nih.gov/pubmed/24454051
http://dx.doi.org/10.1107/S1600536813026342
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(6)O(4), contains three independent mol­ecules (A, B and C). In mol­ecule C, there are two disordered sets of two carbonyl O atoms [occupancies = 0.643 (11) and 0.357 (11)]. All three mol­ecules are non-planar due to repulsion between two O atoms in peri positions on the anthracene ring, showing a slight difference in deviation of the carbonyl O atoms. The intra­molecular distances between the two nearest O atoms are in the range of 2.685 (10)–2.766 (10) Å. In the crystal, mol­ecules are linked by C—H⋯O and π–π [centroid–centroid distances = 3.615 (2), 3.844 (2) and 3.921 (2) Å] inter­actions, which lead to the formation of a herringbone-like arrangement.