2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate

The asymmetric unit of the title compound, C(18)H(16)F(2)N(2)·H(2)O, contains two independent mol­ecules (A and B), and two independent water mol­ecules of crystallization. In mol­ecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-di­fluoro­phenyl and methyl­p...

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Autores principales: Srinivasan, Natesan, Rizwana Begum, Syed Rafee Ahamed, Hema, Ramu, Sridhar, Balasubramanian, Anitha, Azhagan Ganapathi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884277/
https://www.ncbi.nlm.nih.gov/pubmed/24454053
http://dx.doi.org/10.1107/S1600536813026354
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author Srinivasan, Natesan
Rizwana Begum, Syed Rafee Ahamed
Hema, Ramu
Sridhar, Balasubramanian
Anitha, Azhagan Ganapathi
author_facet Srinivasan, Natesan
Rizwana Begum, Syed Rafee Ahamed
Hema, Ramu
Sridhar, Balasubramanian
Anitha, Azhagan Ganapathi
author_sort Srinivasan, Natesan
collection PubMed
description The asymmetric unit of the title compound, C(18)H(16)F(2)N(2)·H(2)O, contains two independent mol­ecules (A and B), and two independent water mol­ecules of crystallization. In mol­ecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-di­fluoro­phenyl and methyl­phenyl rings, respectively. The corresponding angles in mol­ecule B are 45.85 (7) and 62.78 (7)°, respectively. The dihedral angle between the two benzene rings is 64.98 (7)° in mol­ecule A and 65.53 (7)° in mol­ecule B. In the crystal, the two independent mol­ecules are linked by O—H⋯N and O—H⋯O hydrogen bonds, forming chains propagating along [100]. These chains are linked via C—H⋯F hydrogen bonds, forming slab-like two-dimensional networks lying parallel to (001).
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spelling pubmed-38842772014-01-17 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate Srinivasan, Natesan Rizwana Begum, Syed Rafee Ahamed Hema, Ramu Sridhar, Balasubramanian Anitha, Azhagan Ganapathi Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(16)F(2)N(2)·H(2)O, contains two independent mol­ecules (A and B), and two independent water mol­ecules of crystallization. In mol­ecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-di­fluoro­phenyl and methyl­phenyl rings, respectively. The corresponding angles in mol­ecule B are 45.85 (7) and 62.78 (7)°, respectively. The dihedral angle between the two benzene rings is 64.98 (7)° in mol­ecule A and 65.53 (7)° in mol­ecule B. In the crystal, the two independent mol­ecules are linked by O—H⋯N and O—H⋯O hydrogen bonds, forming chains propagating along [100]. These chains are linked via C—H⋯F hydrogen bonds, forming slab-like two-dimensional networks lying parallel to (001). International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884277/ /pubmed/24454053 http://dx.doi.org/10.1107/S1600536813026354 Text en © Srinivasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Srinivasan, Natesan
Rizwana Begum, Syed Rafee Ahamed
Hema, Ramu
Sridhar, Balasubramanian
Anitha, Azhagan Ganapathi
2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title_full 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title_fullStr 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title_full_unstemmed 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title_short 2-(2,4-Di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1H-imidazole monohydrate
title_sort 2-(2,4-di­fluoro­phen­yl)-4,5-dimethyl-1-(4-methyl­phen­yl)-1h-imidazole monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884277/
https://www.ncbi.nlm.nih.gov/pubmed/24454053
http://dx.doi.org/10.1107/S1600536813026354
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