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2-Allyl-7-nitro-2H-indazole

The asymmetric unit of the title compound, C(10)H(9)N(3)O(2), contains two independent mol­ecules linked by a C—H⋯N hydrogen bond. Each mol­ecule has a similar conformation, being built up from fused five- and six-membered rings, each linked to an ally and nitro group, respectively. The indazole rin...

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Autores principales: Kouakou, Assoman, Rakib, El Mostapha, Spinelli, Domenico, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884280/
https://www.ncbi.nlm.nih.gov/pubmed/24454056
http://dx.doi.org/10.1107/S1600536813026743
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author Kouakou, Assoman
Rakib, El Mostapha
Spinelli, Domenico
Saadi, Mohamed
El Ammari, Lahcen
author_facet Kouakou, Assoman
Rakib, El Mostapha
Spinelli, Domenico
Saadi, Mohamed
El Ammari, Lahcen
author_sort Kouakou, Assoman
collection PubMed
description The asymmetric unit of the title compound, C(10)H(9)N(3)O(2), contains two independent mol­ecules linked by a C—H⋯N hydrogen bond. Each mol­ecule has a similar conformation, being built up from fused five- and six-membered rings, each linked to an ally and nitro group, respectively. The indazole ring system makes dihedral angles of 2.7 (2) and 2.2 (2)°, respectively, with the plane through the nitro group. The allyl group is nearly perpendicular to the indazole system, as indicated by the N—N—C—C torsion angles of −75.3 (2) and −82.2 (2)°, this being the most important difference between the conformations of the two mol­ecules. In the crystal, mol­ecules are linked by C—H⋯O and π–π [inter-centroid distance = 3.6225 (8) Å] inter­actions to form a three-dimensional network.
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spelling pubmed-38842802014-01-17 2-Allyl-7-nitro-2H-indazole Kouakou, Assoman Rakib, El Mostapha Spinelli, Domenico Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(9)N(3)O(2), contains two independent mol­ecules linked by a C—H⋯N hydrogen bond. Each mol­ecule has a similar conformation, being built up from fused five- and six-membered rings, each linked to an ally and nitro group, respectively. The indazole ring system makes dihedral angles of 2.7 (2) and 2.2 (2)°, respectively, with the plane through the nitro group. The allyl group is nearly perpendicular to the indazole system, as indicated by the N—N—C—C torsion angles of −75.3 (2) and −82.2 (2)°, this being the most important difference between the conformations of the two mol­ecules. In the crystal, mol­ecules are linked by C—H⋯O and π–π [inter-centroid distance = 3.6225 (8) Å] inter­actions to form a three-dimensional network. International Union of Crystallography 2013-10-02 /pmc/articles/PMC3884280/ /pubmed/24454056 http://dx.doi.org/10.1107/S1600536813026743 Text en © Kouakou et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kouakou, Assoman
Rakib, El Mostapha
Spinelli, Domenico
Saadi, Mohamed
El Ammari, Lahcen
2-Allyl-7-nitro-2H-indazole
title 2-Allyl-7-nitro-2H-indazole
title_full 2-Allyl-7-nitro-2H-indazole
title_fullStr 2-Allyl-7-nitro-2H-indazole
title_full_unstemmed 2-Allyl-7-nitro-2H-indazole
title_short 2-Allyl-7-nitro-2H-indazole
title_sort 2-allyl-7-nitro-2h-indazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884280/
https://www.ncbi.nlm.nih.gov/pubmed/24454056
http://dx.doi.org/10.1107/S1600536813026743
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