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Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate
In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, molecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O interactions generating R (2)...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884285/ https://www.ncbi.nlm.nih.gov/pubmed/24454061 http://dx.doi.org/10.1107/S1600536813026871 |
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author | Suchetan, P. A. Palakshamurthy, B. S. Mohan, N. R. Madan Kumar, S. Lokanath, N. K. Sreenivasa, S. |
author_facet | Suchetan, P. A. Palakshamurthy, B. S. Mohan, N. R. Madan Kumar, S. Lokanath, N. K. Sreenivasa, S. |
author_sort | Suchetan, P. A. |
collection | PubMed |
description | In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, molecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O interactions generating R (2) (2)(10) and R (2) (2)(14) motifs. These dimers are arranged in a zigzag pattern in the crystal structure. The molecules are further linked along the c axis through weak C—H⋯π interactions, and weak π⋯π interactions [centroid–centroid separation = 3.9986 (17) Å] are also observed. |
format | Online Article Text |
id | pubmed-3884285 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842852014-01-17 Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate Suchetan, P. A. Palakshamurthy, B. S. Mohan, N. R. Madan Kumar, S. Lokanath, N. K. Sreenivasa, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, molecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O interactions generating R (2) (2)(10) and R (2) (2)(14) motifs. These dimers are arranged in a zigzag pattern in the crystal structure. The molecules are further linked along the c axis through weak C—H⋯π interactions, and weak π⋯π interactions [centroid–centroid separation = 3.9986 (17) Å] are also observed. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884285/ /pubmed/24454061 http://dx.doi.org/10.1107/S1600536813026871 Text en © Suchetan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suchetan, P. A. Palakshamurthy, B. S. Mohan, N. R. Madan Kumar, S. Lokanath, N. K. Sreenivasa, S. Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title | Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title_full | Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title_fullStr | Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title_full_unstemmed | Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title_short | Ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate |
title_sort | ethyl (2e)-2-cyano-3-(4-methoxyphenyl)acrylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884285/ https://www.ncbi.nlm.nih.gov/pubmed/24454061 http://dx.doi.org/10.1107/S1600536813026871 |
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