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Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate

In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, mol­ecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O inter­actions generating R (2)...

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Autores principales: Suchetan, P. A., Palakshamurthy, B. S., Mohan, N. R., Madan Kumar, S., Lokanath, N. K., Sreenivasa, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884285/
https://www.ncbi.nlm.nih.gov/pubmed/24454061
http://dx.doi.org/10.1107/S1600536813026871
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author Suchetan, P. A.
Palakshamurthy, B. S.
Mohan, N. R.
Madan Kumar, S.
Lokanath, N. K.
Sreenivasa, S.
author_facet Suchetan, P. A.
Palakshamurthy, B. S.
Mohan, N. R.
Madan Kumar, S.
Lokanath, N. K.
Sreenivasa, S.
author_sort Suchetan, P. A.
collection PubMed
description In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, mol­ecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O inter­actions generating R (2) (2)(10) and R (2) (2)(14) motifs. These dimers are arranged in a zigzag pattern in the crystal structure. The mol­ecules are further linked along the c axis through weak C—H⋯π inter­actions, and weak π⋯π inter­actions [centroid–centroid separation = 3.9986 (17) Å] are also observed.
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spelling pubmed-38842852014-01-17 Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate Suchetan, P. A. Palakshamurthy, B. S. Mohan, N. R. Madan Kumar, S. Lokanath, N. K. Sreenivasa, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)NO(3), the conformation across the C=C bond is synperiplanar, the torsion angle of the segment C(ring)—C=C—C(N) being 3.2 (5)°. In the crystal, mol­ecules are linked into inversion dimers, arranged in a zigzag pattern, through two C—H⋯O inter­actions generating R (2) (2)(10) and R (2) (2)(14) motifs. These dimers are arranged in a zigzag pattern in the crystal structure. The mol­ecules are further linked along the c axis through weak C—H⋯π inter­actions, and weak π⋯π inter­actions [centroid–centroid separation = 3.9986 (17) Å] are also observed. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884285/ /pubmed/24454061 http://dx.doi.org/10.1107/S1600536813026871 Text en © Suchetan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suchetan, P. A.
Palakshamurthy, B. S.
Mohan, N. R.
Madan Kumar, S.
Lokanath, N. K.
Sreenivasa, S.
Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title_full Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title_fullStr Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title_full_unstemmed Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title_short Ethyl (2E)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
title_sort ethyl (2e)-2-cyano-3-(4-meth­oxy­phen­yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884285/
https://www.ncbi.nlm.nih.gov/pubmed/24454061
http://dx.doi.org/10.1107/S1600536813026871
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