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4-Amino-N-(4,6-di­methyl­pyrimidin-2-yl)benzene­sulfonamide–1,4-di­aza­bicyclo­[2.2.2]octane (2/1)

The asymmetric unit of the title co-crystal, C(12)H(14)N(4)O(2)S·0.5C(6)H(12)N(2), comprises the sulfonamide mol­ecule and half a mol­ecule of 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO), the latter being disposed about a crystallographic twofold rotation axis. In the sulfonamide mol­ecule, the aromati...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Kaulgud, Trupta, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884290/
https://www.ncbi.nlm.nih.gov/pubmed/24454066
http://dx.doi.org/10.1107/S1600536813027037
Descripción
Sumario:The asymmetric unit of the title co-crystal, C(12)H(14)N(4)O(2)S·0.5C(6)H(12)N(2), comprises the sulfonamide mol­ecule and half a mol­ecule of 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO), the latter being disposed about a crystallographic twofold rotation axis. In the sulfonamide mol­ecule, the aromatic rings are almost perpendicular to one another [dihedral angle = 75.01 (8)°]. In the crystal, mol­ecules are connected into a three-mol­ecule aggregate via amide–DABCO N—H⋯N hydrogen bonds, and these are connected into a three-dimensional architecture via amino–DABCO N—H⋯O and amino-pyrimidine N—H⋯N hydrogen bonds.