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2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)

The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)eth­yl]pyridine mol­ecule and a 2-amino­benzoic acid mol­ecule in a general position. The acid has a small twist between the carb­oxy­lic acid residue and the ring [dihedral ang...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884291/
https://www.ncbi.nlm.nih.gov/pubmed/24454067
http://dx.doi.org/10.1107/S1600536813027128
Descripción
Sumario:The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)eth­yl]pyridine mol­ecule and a 2-amino­benzoic acid mol­ecule in a general position. The acid has a small twist between the carb­oxy­lic acid residue and the ring [dihedral angle = 7.13 (6)°] despite the presence of an intra­molecular N—H⋯O(carbon­yl) hydrogen bond. Three-mol­ecule aggregates are formed via O—H⋯N(pyrid­yl) hydrogen bonds, and these are connected into supra­molecular layers in the bc plane by N—H⋯O(carbon­yl) hydrogen bonds and π–π inter­actions between pyridine and benzene rings [inter-centroid distance = 3.6332 (9) Å]. Layers are connected along the a axis by weak π–π inter­actions between benzene rings [3.9577 (10) Å].