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2-Aminobenzoic acid–4-[2-(pyridin-4-yl)ethyl]pyridine (2/1)
The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)ethyl]pyridine molecule and a 2-aminobenzoic acid molecule in a general position. The acid has a small twist between the carboxylic acid residue and the ring [dihedral ang...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884291/ https://www.ncbi.nlm.nih.gov/pubmed/24454067 http://dx.doi.org/10.1107/S1600536813027128 |
Sumario: | The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)ethyl]pyridine molecule and a 2-aminobenzoic acid molecule in a general position. The acid has a small twist between the carboxylic acid residue and the ring [dihedral angle = 7.13 (6)°] despite the presence of an intramolecular N—H⋯O(carbonyl) hydrogen bond. Three-molecule aggregates are formed via O—H⋯N(pyridyl) hydrogen bonds, and these are connected into supramolecular layers in the bc plane by N—H⋯O(carbonyl) hydrogen bonds and π–π interactions between pyridine and benzene rings [inter-centroid distance = 3.6332 (9) Å]. Layers are connected along the a axis by weak π–π interactions between benzene rings [3.9577 (10) Å]. |
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