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2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)

The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)eth­yl]pyridine mol­ecule and a 2-amino­benzoic acid mol­ecule in a general position. The acid has a small twist between the carb­oxy­lic acid residue and the ring [dihedral ang...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884291/
https://www.ncbi.nlm.nih.gov/pubmed/24454067
http://dx.doi.org/10.1107/S1600536813027128
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author Arman, Hadi D.
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)eth­yl]pyridine mol­ecule and a 2-amino­benzoic acid mol­ecule in a general position. The acid has a small twist between the carb­oxy­lic acid residue and the ring [dihedral angle = 7.13 (6)°] despite the presence of an intra­molecular N—H⋯O(carbon­yl) hydrogen bond. Three-mol­ecule aggregates are formed via O—H⋯N(pyrid­yl) hydrogen bonds, and these are connected into supra­molecular layers in the bc plane by N—H⋯O(carbon­yl) hydrogen bonds and π–π inter­actions between pyridine and benzene rings [inter-centroid distance = 3.6332 (9) Å]. Layers are connected along the a axis by weak π–π inter­actions between benzene rings [3.9577 (10) Å].
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spelling pubmed-38842912014-01-17 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1) Arman, Hadi D. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title co-crystal, C(12)H(12)N(2)·2C(7)H(7)NO(2), comprises a centrosymmetric 4-[2-(pyridin-4-yl)eth­yl]pyridine mol­ecule and a 2-amino­benzoic acid mol­ecule in a general position. The acid has a small twist between the carb­oxy­lic acid residue and the ring [dihedral angle = 7.13 (6)°] despite the presence of an intra­molecular N—H⋯O(carbon­yl) hydrogen bond. Three-mol­ecule aggregates are formed via O—H⋯N(pyrid­yl) hydrogen bonds, and these are connected into supra­molecular layers in the bc plane by N—H⋯O(carbon­yl) hydrogen bonds and π–π inter­actions between pyridine and benzene rings [inter-centroid distance = 3.6332 (9) Å]. Layers are connected along the a axis by weak π–π inter­actions between benzene rings [3.9577 (10) Å]. International Union of Crystallography 2013-10-05 /pmc/articles/PMC3884291/ /pubmed/24454067 http://dx.doi.org/10.1107/S1600536813027128 Text en © Arman and Tiekink 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arman, Hadi D.
Tiekink, Edward R. T.
2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title_full 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title_fullStr 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title_full_unstemmed 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title_short 2-Amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
title_sort 2-amino­benzoic acid–4-[2-(pyridin-4-yl)eth­yl]pyridine (2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884291/
https://www.ncbi.nlm.nih.gov/pubmed/24454067
http://dx.doi.org/10.1107/S1600536813027128
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