3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation

The asymmetric unit of title hydrated salt, C(22)H(46)N(4) (2+)·2Cl(−)·4H(2)O, comprises half a centrosymmetric dication, one Cl(−) anion and two water mol­ecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine N atoms, and that the...

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Detalles Bibliográficos
Autores principales: Moon, Dohyun, Subhan, Md Abdus, Choi, Jong-Ha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884294/
https://www.ncbi.nlm.nih.gov/pubmed/24454070
http://dx.doi.org/10.1107/S1600536813027232
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author Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
author_facet Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
author_sort Moon, Dohyun
collection PubMed
description The asymmetric unit of title hydrated salt, C(22)H(46)N(4) (2+)·2Cl(−)·4H(2)O, comprises half a centrosymmetric dication, one Cl(−) anion and two water mol­ecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine N atoms, and that the dication features intra­molecular N—H⋯N hydrogen bonds. In the crystal, a three-dimensional artchitecture is formed by O—H⋯Cl/N and N—H⋯Cl/O hydrogen bonds.
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spelling pubmed-38842942014-01-17 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of title hydrated salt, C(22)H(46)N(4) (2+)·2Cl(−)·4H(2)O, comprises half a centrosymmetric dication, one Cl(−) anion and two water mol­ecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine N atoms, and that the dication features intra­molecular N—H⋯N hydrogen bonds. In the crystal, a three-dimensional artchitecture is formed by O—H⋯Cl/N and N—H⋯Cl/O hydrogen bonds. International Union of Crystallography 2013-10-09 /pmc/articles/PMC3884294/ /pubmed/24454070 http://dx.doi.org/10.1107/S1600536813027232 Text en © Moon et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title_full 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title_fullStr 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title_full_unstemmed 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title_short 3,14-Diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
title_sort 3,14-diethyl-2,13-di­aza-6,17-diazonia­tri­cyclo­[16.4.0.0(7,12)]docosane dichloride tetra­hydrate from synchrotron radiation
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884294/
https://www.ncbi.nlm.nih.gov/pubmed/24454070
http://dx.doi.org/10.1107/S1600536813027232
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AT choijongha 314diethyl213diaza617diazoniatricyclo16400712docosanedichloridetetrahydratefromsynchrotronradiation

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