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2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}

The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent mol­ecules with similar conformations. The di­hydro­naphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two di­hyd...

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Autores principales: Hakberdiev, Shukhrat M., Talipov, Samat A., Dalimov, Davranbek N., Ibragimov, Bakhtiyar T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884299/
https://www.ncbi.nlm.nih.gov/pubmed/24454075
http://dx.doi.org/10.1107/S1600536813027281
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author Hakberdiev, Shukhrat M.
Talipov, Samat A.
Dalimov, Davranbek N.
Ibragimov, Bakhtiyar T.
author_facet Hakberdiev, Shukhrat M.
Talipov, Samat A.
Dalimov, Davranbek N.
Ibragimov, Bakhtiyar T.
author_sort Hakberdiev, Shukhrat M.
collection PubMed
description The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent mol­ecules with similar conformations. The di­hydro­naphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two di­hydro­naphthalene ring systems is 83.37 (4)° in one mol­ecule and 88.99 (4)° in the other. The carbonyl O atom is linked with the adjacent hy­droxy and imino groups via intra­molecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked through O—H⋯O hydrogen bonds into layers parallel to (001), and adjacent layers are further stacked by π–π inter­actions between di­hydro­naphthalene and phenyl rings into a three-dimensional supra­molecular architecture. In the crystal, one of the isopropyl groups is disordered over two positions with an occupancy ratio of 0.684 (8):0.316 (8).
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spelling pubmed-38842992014-01-17 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one} Hakberdiev, Shukhrat M. Talipov, Samat A. Dalimov, Davranbek N. Ibragimov, Bakhtiyar T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent mol­ecules with similar conformations. The di­hydro­naphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two di­hydro­naphthalene ring systems is 83.37 (4)° in one mol­ecule and 88.99 (4)° in the other. The carbonyl O atom is linked with the adjacent hy­droxy and imino groups via intra­molecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked through O—H⋯O hydrogen bonds into layers parallel to (001), and adjacent layers are further stacked by π–π inter­actions between di­hydro­naphthalene and phenyl rings into a three-dimensional supra­molecular architecture. In the crystal, one of the isopropyl groups is disordered over two positions with an occupancy ratio of 0.684 (8):0.316 (8). International Union of Crystallography 2013-10-09 /pmc/articles/PMC3884299/ /pubmed/24454075 http://dx.doi.org/10.1107/S1600536813027281 Text en © Hakberdiev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hakberdiev, Shukhrat M.
Talipov, Samat A.
Dalimov, Davranbek N.
Ibragimov, Bakhtiyar T.
2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title_full 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title_fullStr 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title_full_unstemmed 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title_short 2,2′-Bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8H)-one}
title_sort 2,2′-bis{8-[(benzyl­amino)­methyl­idene]-1,6-dihy­droxy-5-isopropyl-3-methyl­naphthalen-7(8h)-one}
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884299/
https://www.ncbi.nlm.nih.gov/pubmed/24454075
http://dx.doi.org/10.1107/S1600536813027281
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