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2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one}
The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent molecules with similar conformations. The dihydronaphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two dihyd...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884299/ https://www.ncbi.nlm.nih.gov/pubmed/24454075 http://dx.doi.org/10.1107/S1600536813027281 |
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author | Hakberdiev, Shukhrat M. Talipov, Samat A. Dalimov, Davranbek N. Ibragimov, Bakhtiyar T. |
author_facet | Hakberdiev, Shukhrat M. Talipov, Samat A. Dalimov, Davranbek N. Ibragimov, Bakhtiyar T. |
author_sort | Hakberdiev, Shukhrat M. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent molecules with similar conformations. The dihydronaphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two dihydronaphthalene ring systems is 83.37 (4)° in one molecule and 88.99 (4)° in the other. The carbonyl O atom is linked with the adjacent hydroxy and imino groups via intramolecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal, molecules are linked through O—H⋯O hydrogen bonds into layers parallel to (001), and adjacent layers are further stacked by π–π interactions between dihydronaphthalene and phenyl rings into a three-dimensional supramolecular architecture. In the crystal, one of the isopropyl groups is disordered over two positions with an occupancy ratio of 0.684 (8):0.316 (8). |
format | Online Article Text |
id | pubmed-3884299 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38842992014-01-17 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} Hakberdiev, Shukhrat M. Talipov, Samat A. Dalimov, Davranbek N. Ibragimov, Bakhtiyar T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(44)H(44)N(2)O(6), contains two independent molecules with similar conformations. The dihydronaphthalene ring systems are approximately planar [maximum deviations = 0.036 (2), 0.128 (2), 0.0.24 (2) and 0.075 (2) Å]. The dihedral angle between two dihydronaphthalene ring systems is 83.37 (4)° in one molecule and 88.99 (4)° in the other. The carbonyl O atom is linked with the adjacent hydroxy and imino groups via intramolecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal, molecules are linked through O—H⋯O hydrogen bonds into layers parallel to (001), and adjacent layers are further stacked by π–π interactions between dihydronaphthalene and phenyl rings into a three-dimensional supramolecular architecture. In the crystal, one of the isopropyl groups is disordered over two positions with an occupancy ratio of 0.684 (8):0.316 (8). International Union of Crystallography 2013-10-09 /pmc/articles/PMC3884299/ /pubmed/24454075 http://dx.doi.org/10.1107/S1600536813027281 Text en © Hakberdiev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hakberdiev, Shukhrat M. Talipov, Samat A. Dalimov, Davranbek N. Ibragimov, Bakhtiyar T. 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title | 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title_full | 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title_fullStr | 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title_full_unstemmed | 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title_short | 2,2′-Bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8H)-one} |
title_sort | 2,2′-bis{8-[(benzylamino)methylidene]-1,6-dihydroxy-5-isopropyl-3-methylnaphthalen-7(8h)-one} |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884299/ https://www.ncbi.nlm.nih.gov/pubmed/24454075 http://dx.doi.org/10.1107/S1600536813027281 |
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