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4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)

In the asymmetric unit of the title salt, C(14)H(18)N(2)O(2+)·2CF(3)O(3)S(−), the components are linked by two N—H⋯O and one C—H⋯O hydrogen bonds. The dipyridinium salt demonstrates a skew conformation based upon C—O—C—C torsion angles of 61.5 (3) and 15.1 (4)°. A C—O—C angle of 119.3 (2)° and C—O b...

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Autores principales: Stubbs, Amanda W., Golen, James A., Rheingold, Arnold L., Manke, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884303/
https://www.ncbi.nlm.nih.gov/pubmed/24454079
http://dx.doi.org/10.1107/S1600536813027505
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author Stubbs, Amanda W.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
author_facet Stubbs, Amanda W.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
author_sort Stubbs, Amanda W.
collection PubMed
description In the asymmetric unit of the title salt, C(14)H(18)N(2)O(2+)·2CF(3)O(3)S(−), the components are linked by two N—H⋯O and one C—H⋯O hydrogen bonds. The dipyridinium salt demonstrates a skew conformation based upon C—O—C—C torsion angles of 61.5 (3) and 15.1 (4)°. A C—O—C angle of 119.3 (2)° and C—O bond distances of 1.364 (3) and 1.389 (3) Å are consistent with other dipyridyl ethers. The planes of the pyridyl rings exhibit a twist angle of 67.89 (8)°. One of the tri­fluoro­methane­sulfonate ions shows disorder of the F atoms [in a 0.52 (7):0.48 (7) occupancy ratio] and an O atom [0.64 (8):0.36 (8) occupancy ratio]. In the crystal, the components are linked by C—H⋯O inter­actions, which form chains along [101].
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spelling pubmed-38843032014-01-17 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate) Stubbs, Amanda W. Golen, James A. Rheingold, Arnold L. Manke, David R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title salt, C(14)H(18)N(2)O(2+)·2CF(3)O(3)S(−), the components are linked by two N—H⋯O and one C—H⋯O hydrogen bonds. The dipyridinium salt demonstrates a skew conformation based upon C—O—C—C torsion angles of 61.5 (3) and 15.1 (4)°. A C—O—C angle of 119.3 (2)° and C—O bond distances of 1.364 (3) and 1.389 (3) Å are consistent with other dipyridyl ethers. The planes of the pyridyl rings exhibit a twist angle of 67.89 (8)°. One of the tri­fluoro­methane­sulfonate ions shows disorder of the F atoms [in a 0.52 (7):0.48 (7) occupancy ratio] and an O atom [0.64 (8):0.36 (8) occupancy ratio]. In the crystal, the components are linked by C—H⋯O inter­actions, which form chains along [101]. International Union of Crystallography 2013-10-12 /pmc/articles/PMC3884303/ /pubmed/24454079 http://dx.doi.org/10.1107/S1600536813027505 Text en © Stubbs et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Stubbs, Amanda W.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title_full 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title_fullStr 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title_full_unstemmed 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title_short 4,4′-Oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
title_sort 4,4′-oxybis(2,6-di­methyl­pyridinium) bis­(tri­fluoro­methane­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884303/
https://www.ncbi.nlm.nih.gov/pubmed/24454079
http://dx.doi.org/10.1107/S1600536813027505
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