Cargando…

N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate

In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral a...

Descripción completa

Detalles Bibliográficos
Autores principales: Garza Rodríguez, Luis Ángel, Elizondo Martínez, Perla, Bernès, Sylvain, Nájera Martínez, Blanca, Pérez Rodríguez, Nancy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884311/
https://www.ncbi.nlm.nih.gov/pubmed/24454087
http://dx.doi.org/10.1107/S1600536813027475
_version_ 1782298561376944128
author Garza Rodríguez, Luis Ángel
Elizondo Martínez, Perla
Bernès, Sylvain
Nájera Martínez, Blanca
Pérez Rodríguez, Nancy
author_facet Garza Rodríguez, Luis Ángel
Elizondo Martínez, Perla
Bernès, Sylvain
Nájera Martínez, Blanca
Pérez Rodríguez, Nancy
author_sort Garza Rodríguez, Luis Ángel
collection PubMed
description In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6)°. The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—H⋯O inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R (4) (4)(18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—H⋯O hydrogen bonds with the nitrate O atoms, and there are also a number of C—H⋯O hydrogen bonds present. The resulting supra­molecular structure is based on a two-dimensional network extending in the ab plane.
format Online
Article
Text
id pubmed-3884311
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38843112014-01-17 N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6)°. The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—H⋯O inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R (4) (4)(18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—H⋯O hydrogen bonds with the nitrate O atoms, and there are also a number of C—H⋯O hydrogen bonds present. The resulting supra­molecular structure is based on a two-dimensional network extending in the ab plane. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884311/ /pubmed/24454087 http://dx.doi.org/10.1107/S1600536813027475 Text en © Garza Rodríguez et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Garza Rodríguez, Luis Ángel
Elizondo Martínez, Perla
Bernès, Sylvain
Nájera Martínez, Blanca
Pérez Rodríguez, Nancy
N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title_full N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title_fullStr N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title_full_unstemmed N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title_short N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
title_sort n,n′-bis(2-amino­benz­yl)ethane-1,2-diaminium dinitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884311/
https://www.ncbi.nlm.nih.gov/pubmed/24454087
http://dx.doi.org/10.1107/S1600536813027475
work_keys_str_mv AT garzarodriguezluisangel nnbis2aminobenzylethane12diaminiumdinitrate
AT elizondomartinezperla nnbis2aminobenzylethane12diaminiumdinitrate
AT bernessylvain nnbis2aminobenzylethane12diaminiumdinitrate
AT najeramartinezblanca nnbis2aminobenzylethane12diaminiumdinitrate
AT perezrodrigueznancy nnbis2aminobenzylethane12diaminiumdinitrate