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N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate
In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884311/ https://www.ncbi.nlm.nih.gov/pubmed/24454087 http://dx.doi.org/10.1107/S1600536813027475 |
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author | Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy |
author_facet | Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy |
author_sort | Garza Rodríguez, Luis Ángel |
collection | PubMed |
description | In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6)°. The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—H⋯O inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R (4) (4)(18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—H⋯O hydrogen bonds with the nitrate O atoms, and there are also a number of C—H⋯O hydrogen bonds present. The resulting supramolecular structure is based on a two-dimensional network extending in the ab plane. |
format | Online Article Text |
id | pubmed-3884311 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38843112014-01-17 N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(16)H(24)N(4) (2+)·2NO(3) (−), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6)°. The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—H⋯O inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R (4) (4)(18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—H⋯O hydrogen bonds with the nitrate O atoms, and there are also a number of C—H⋯O hydrogen bonds present. The resulting supramolecular structure is based on a two-dimensional network extending in the ab plane. International Union of Crystallography 2013-10-16 /pmc/articles/PMC3884311/ /pubmed/24454087 http://dx.doi.org/10.1107/S1600536813027475 Text en © Garza Rodríguez et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title_full |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title_fullStr |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title_full_unstemmed |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title_short |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
title_sort | n,n′-bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884311/ https://www.ncbi.nlm.nih.gov/pubmed/24454087 http://dx.doi.org/10.1107/S1600536813027475 |
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