(6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one

The title compound, C(11)H(18)O(5), was isolated from a liquid culture of Pestalotiopsis sp. In the mol­ecule, the pyran-2-one ring assumes a half-chair conformation. The two terminal C atoms of the pentyl group were refined as disordered over two sets of sites, with refined occupancies of 0.881 (10...

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Detalles Bibliográficos
Autores principales: Valenti, Domenic J., Arif, Atta M., Strobel, Gary A., Harper, James K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884319/
https://www.ncbi.nlm.nih.gov/pubmed/24454095
http://dx.doi.org/10.1107/S1600536813027025
Descripción
Sumario:The title compound, C(11)H(18)O(5), was isolated from a liquid culture of Pestalotiopsis sp. In the mol­ecule, the pyran-2-one ring assumes a half-chair conformation. The two terminal C atoms of the pentyl group were refined as disordered over two sets of sites, with refined occupancies of 0.881 (10) and 0.119 (10). In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds forming a three-dimensional network.

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