(6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one

The title compound, C(11)H(18)O(5), was isolated from a liquid culture of Pestalotiopsis sp. In the mol­ecule, the pyran-2-one ring assumes a half-chair conformation. The two terminal C atoms of the pentyl group were refined as disordered over two sets of sites, with refined occupancies of 0.881 (10...

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Detalles Bibliográficos
Autores principales: Valenti, Domenic J., Arif, Atta M., Strobel, Gary A., Harper, James K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884319/
https://www.ncbi.nlm.nih.gov/pubmed/24454095
http://dx.doi.org/10.1107/S1600536813027025
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author Valenti, Domenic J.
Arif, Atta M.
Strobel, Gary A.
Harper, James K.
author_facet Valenti, Domenic J.
Arif, Atta M.
Strobel, Gary A.
Harper, James K.
author_sort Valenti, Domenic J.
collection PubMed
description The title compound, C(11)H(18)O(5), was isolated from a liquid culture of Pestalotiopsis sp. In the mol­ecule, the pyran-2-one ring assumes a half-chair conformation. The two terminal C atoms of the pentyl group were refined as disordered over two sets of sites, with refined occupancies of 0.881 (10) and 0.119 (10). In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds forming a three-dimensional network.
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spelling pubmed-38843192014-01-17 (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one Valenti, Domenic J. Arif, Atta M. Strobel, Gary A. Harper, James K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(18)O(5), was isolated from a liquid culture of Pestalotiopsis sp. In the mol­ecule, the pyran-2-one ring assumes a half-chair conformation. The two terminal C atoms of the pentyl group were refined as disordered over two sets of sites, with refined occupancies of 0.881 (10) and 0.119 (10). In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds forming a three-dimensional network. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884319/ /pubmed/24454095 http://dx.doi.org/10.1107/S1600536813027025 Text en © Valenti et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Valenti, Domenic J.
Arif, Atta M.
Strobel, Gary A.
Harper, James K.
(6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title_full (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title_fullStr (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title_full_unstemmed (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title_short (6S*)-6-[(1S*,2R*)-1,2-Di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2H-pyran-2-one
title_sort (6s*)-6-[(1s*,2r*)-1,2-di­hydroxy­pent­yl]-4-meth­oxy-5,6-di­hydro-2h-pyran-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884319/
https://www.ncbi.nlm.nih.gov/pubmed/24454095
http://dx.doi.org/10.1107/S1600536813027025
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