Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane

In the title compound, C(25)H(32)N(4)O(4), both piperazine rings adopt a chair conformation. One of dioxolane ring systems is essentially planar [dihedral angle = 0.9 (2)°] while the other adopts a slightly disordered envelope conformation, the mean plane of the dioxolane ring being twisted by 3.6 (...

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Autores principales: Kavitha, Channappa N., Jasinski, Jerry P., Anderson, Brian J., Yathirajan, H. S., Kaur, Manpreet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884327/
https://www.ncbi.nlm.nih.gov/pubmed/24454103
http://dx.doi.org/10.1107/S1600536813028109
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author Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H. S.
Kaur, Manpreet
author_facet Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H. S.
Kaur, Manpreet
author_sort Kavitha, Channappa N.
collection PubMed
description In the title compound, C(25)H(32)N(4)O(4), both piperazine rings adopt a chair conformation. One of dioxolane ring systems is essentially planar [dihedral angle = 0.9 (2)°] while the other adopts a slightly disordered envelope conformation, the mean plane of the dioxolane ring being twisted by 3.6 (2)° from that of the benzene ring. The dihedral angle between the benzene rings is 69.9 (5)°. No classical hydrogen bonds were observed.
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spelling pubmed-38843272014-01-17 Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane Kavitha, Channappa N. Jasinski, Jerry P. Anderson, Brian J. Yathirajan, H. S. Kaur, Manpreet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(32)N(4)O(4), both piperazine rings adopt a chair conformation. One of dioxolane ring systems is essentially planar [dihedral angle = 0.9 (2)°] while the other adopts a slightly disordered envelope conformation, the mean plane of the dioxolane ring being twisted by 3.6 (2)° from that of the benzene ring. The dihedral angle between the benzene rings is 69.9 (5)°. No classical hydrogen bonds were observed. International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884327/ /pubmed/24454103 http://dx.doi.org/10.1107/S1600536813028109 Text en © Kavitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H. S.
Kaur, Manpreet
Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title_full Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title_fullStr Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title_full_unstemmed Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title_short Bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
title_sort bis{4-[(1,3-benzodioxol-5-yl)meth­yl]piperazin-1-yl}methane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884327/
https://www.ncbi.nlm.nih.gov/pubmed/24454103
http://dx.doi.org/10.1107/S1600536813028109
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