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Methyl 2-[4-(tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoate

In the title compound, C(15)H(13)F(3)O(2)S, the dihedral angle between the benzene rings is 79.5 (1)°. The ester group is twisted by 7.6 (1)° from the mean plane of the adjacent benzene ring. Disorder was modeled over two sites for one F atom of the tri­fluoro­methyl group with an occupancy ratio of...

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Detalles Bibliográficos
Autores principales: Yamuna, Thammarse S., Jasinski, Jerry P., Anderson, Brian J., Yathirajan, H. S., Kaur, Manpreet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884328/
https://www.ncbi.nlm.nih.gov/pubmed/24454104
http://dx.doi.org/10.1107/S1600536813028146
Descripción
Sumario:In the title compound, C(15)H(13)F(3)O(2)S, the dihedral angle between the benzene rings is 79.5 (1)°. The ester group is twisted by 7.6 (1)° from the mean plane of the adjacent benzene ring. Disorder was modeled over two sites for one F atom of the tri­fluoro­methyl group with an occupancy ratio of 0.54 (6):0.46 (6). In the crystal, mol­ecules are linked via weak C—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (101). The networks are linked via C—H⋯π inter­actions, leading to the formation of a three-dimensional supra­molecular structure.